新型钙钛矿基MASnBr3串联光伏电池的数值研究

Shreyus Goutham Kumar, Suraj N, Tadi Surya Teja Reddy, Prashanth Cr, G. Honnavar
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摘要

最近光伏研究的主要目标是通过实验研究或建模和仿真来开发一种极其高效和稳定的设备。单结太阳能电池的性能主要受到热化损耗和传输损耗的限制。因此,串联太阳能电池(TSC)对有效利用整个太阳光谱和减少这些损失的光子研究产生了重大影响。钙钛矿在硅串联器件上的快速生长得到了钙钛矿材料稳定性的改善和先进硅制造工艺的支持。在本文中,我们使用SCAPS软件检查了c-Si(带隙:1.12 eV)作为最底部亚电池的TSC和无铅有机-无机杂化PSC,即MASnBr3(带隙:1.3 eV),其中MA=甲基铵(CH3NH3)作为最顶部亚电池。独立顶电池的效率(eta)为32.98 (FF=88.19, Jsc= 33.89, Voc=1.10)。独立底部电池的效率(eta)为21.71 (FF=85.23, Jsc=18.84, Voc=0.73)。在c-Si上添加MASnBr3的TSC的效率为44.35 (FF=82.94, Jsc=15.25, Voc=1.91)。这些结果表明,使用无毒材料(如MASnBr3)获得更高的PCE值是可行的。
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Numerical Study on novel MASnBr3 (Perovskite) based Tandem Photovoltaic Cell
The main goal of the most recent photovoltaic studies is to develop a device that is extremely efficient and stable, either through experimental study or through modeling and simulation. The single junction solar cell’s performance is mainly limited by thermalization loss and transmission loss. Due to this, tandem solar cells (TSC) have had a significant impact on photonic studies to effectively use the entire sun spectrum and to reduce these losses. The quick growth of perovskite on silicon Tandem devices has been supported by improvements in perovskite material stability and advanced silicon fabrication processes. In this paper, we use SCAPS software to check out a TSC with the c-Si (bandgap: 1.12 eV) as the bottommost subcell and the lead–free organic–inorganic hybrid PSC i.e., MASnBr3 (bandgap: 1.3 eV) where MA= Methyl Ammonium (CH3NH3) as the topmost subcell. The standalone top cell gives an Efficiency (eta) of 32.98 (FF=88.19, Jsc= 33.89, Voc=1.10). The standalone bottom cell gives an Efficiency (eta) of 21.71 (FF=85.23, Jsc=18.84, Voc=0.73). A TSC with MASnBr3 on c-Si shows an Efficiency of 44.35 (FF=82.94, Jsc=15.25, Voc=1.91). These results showcase the feasibility of using non-toxic materials, such as MASnBr3 to attain higher PCE values.
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