碳化聚苯胺作为C=C双键和硝基有机底物分子氢加氢催化剂的研究

IF 0.7 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Theoretical and Experimental Chemistry Pub Date : 2023-10-28 DOI:10.1007/s11237-023-09778-1
Ya. I. Kurys, I. B. Bychko, O. O. Pariiska, O. Z. Didenko, D. O. Mazur, P. E. Strizhak, V. G. Koshechko, V. D. Pokhodenko
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引用次数: 0

摘要

以聚苯胺(祖母绿碱)为原料,在还原气氛下热解制备了具有大表面积、微孔和中孔的氮掺杂碳。发现这种材料的表层含有吡啶、吡咯和季位构型的氮,以及羟基和羰基。结果表明,碳化聚苯胺在含C=C双键和硝基(乙烯、α-甲基苯乙烯、对硝基甲苯)的有机底物的气相加氢和液相加氢过程中表现出催化性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Carbonized Polyaniline as a Catalyst for Hydrogenation with Molecular Hydrogen of Organic Substrates with C=C Double Bond and Nitro Group

Nitrogen-doped carbon, which is characterized by a large surface area and the presence of micro- and mesopores, has been obtained by pyrolysis of polyaniline (emeraldine base) in a reducing atmosphere. It is found that the surface layer of such material contains nitrogen in pyridinic, pyrrolic, and quaternary configurations, as well as hydroxyl and carbonyl groups. It is shown that carbonized polyaniline reveals catalytic properties in the processes of gas-phase and liquid-phase hydrogenation with molecular hydrogen of organic substrates containing C=C double bond and nitro group (ethylene, α-methylstyrene, p-nitrotoluene) are revealed.

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来源期刊
Theoretical and Experimental Chemistry
Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.60
自引率
10.00%
发文量
30
审稿时长
6-12 weeks
期刊介绍: Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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