{"title":"天然斜沸石分子筛骨架组成对Na+和Ca2+交换的影响","authors":"D. A. Krysenko, V. Ya. Demchenko","doi":"10.1007/s11237-023-09782-5","DOIUrl":null,"url":null,"abstract":"<div><div><p>The effect of the zeolite framework composition on the selectivity and thermodynamic parameters of ion exchange is studied for the exchange reaction of Ca<sup>2+</sup> cations on Na-forms of clinoptilolites from nine deposits of Central and Southeast Europe, Northeast Asia, and North America. An increase in the thermodynamic affinity of Na-forms towards Ca<sup>2+</sup> cations is shown with a decrease in the Si/Al ratio in their zeolite framework.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"59 3","pages":"222 - 230"},"PeriodicalIF":0.7000,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of the Composition of the Zeolite Framework of Natural Clinoptilolites on the Exchange of Cations Na+ On Ca2+\",\"authors\":\"D. A. Krysenko, V. Ya. Demchenko\",\"doi\":\"10.1007/s11237-023-09782-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>The effect of the zeolite framework composition on the selectivity and thermodynamic parameters of ion exchange is studied for the exchange reaction of Ca<sup>2+</sup> cations on Na-forms of clinoptilolites from nine deposits of Central and Southeast Europe, Northeast Asia, and North America. An increase in the thermodynamic affinity of Na-forms towards Ca<sup>2+</sup> cations is shown with a decrease in the Si/Al ratio in their zeolite framework.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"59 3\",\"pages\":\"222 - 230\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-10-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-023-09782-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-023-09782-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of the Composition of the Zeolite Framework of Natural Clinoptilolites on the Exchange of Cations Na+ On Ca2+
The effect of the zeolite framework composition on the selectivity and thermodynamic parameters of ion exchange is studied for the exchange reaction of Ca2+ cations on Na-forms of clinoptilolites from nine deposits of Central and Southeast Europe, Northeast Asia, and North America. An increase in the thermodynamic affinity of Na-forms towards Ca2+ cations is shown with a decrease in the Si/Al ratio in their zeolite framework.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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