{"title":"硫与石墨氮化碳在铜纳米颗粒中的掺入及其在超级电容器中的应用","authors":"Karamveer Sheoran, Nishu Devi, Samarjeet Singh Siwal","doi":"10.37819/nanofab.8.336","DOIUrl":null,"url":null,"abstract":"The incorporation of S-g-C3N4 into CuNPs resulted in enhanced electrochemical performance. The introduction of sulfur facilitated the formation of a highly conductive network within the composite material, enabling effective charge transfer and improved specific capacitance. The g-C3N4 matrix served as a support network, controlling the accumulation of CuNPs and delivering stability during electrochemical cycling. The optimized S-g-C3N4/CuNPs composite showed superior electrochemical performance, high specific capacitance, and enhanced cycling stability. In this study, a facile and scalable synthesis method was employed to fabricate S-g-C3N4/CuNPs composite materials on GCE. The resulting composites were characterized using different optical and microscopic techniques. The electrochemical performance of the nanocomposites was assessed via using different techniques such as cyclic voltammetry (CV), and galvanostatic charge-discharge (GCD) techniques. The S-g-C3N4/CuNPs nanocomposite exhibited excellent electrochemical properties with a specific capacitance of 1944.18 F/g at a current density of 0.5 A/g and excellent cycling stability. The resultant composite material exhibits excellent electrochemical performance, making it an advantageous nominee for energy storage applications needing high power density, extended cycling life, and steadfast performance.","PeriodicalId":51992,"journal":{"name":"Nanofabrication","volume":"6 2","pages":"0"},"PeriodicalIF":3.3000,"publicationDate":"2023-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Incorporation of sulfur with graphitic carbon nitride into copper nanoparticles toward supercapacitor application\",\"authors\":\"Karamveer Sheoran, Nishu Devi, Samarjeet Singh Siwal\",\"doi\":\"10.37819/nanofab.8.336\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The incorporation of S-g-C3N4 into CuNPs resulted in enhanced electrochemical performance. The introduction of sulfur facilitated the formation of a highly conductive network within the composite material, enabling effective charge transfer and improved specific capacitance. The g-C3N4 matrix served as a support network, controlling the accumulation of CuNPs and delivering stability during electrochemical cycling. The optimized S-g-C3N4/CuNPs composite showed superior electrochemical performance, high specific capacitance, and enhanced cycling stability. In this study, a facile and scalable synthesis method was employed to fabricate S-g-C3N4/CuNPs composite materials on GCE. The resulting composites were characterized using different optical and microscopic techniques. The electrochemical performance of the nanocomposites was assessed via using different techniques such as cyclic voltammetry (CV), and galvanostatic charge-discharge (GCD) techniques. The S-g-C3N4/CuNPs nanocomposite exhibited excellent electrochemical properties with a specific capacitance of 1944.18 F/g at a current density of 0.5 A/g and excellent cycling stability. The resultant composite material exhibits excellent electrochemical performance, making it an advantageous nominee for energy storage applications needing high power density, extended cycling life, and steadfast performance.\",\"PeriodicalId\":51992,\"journal\":{\"name\":\"Nanofabrication\",\"volume\":\"6 2\",\"pages\":\"0\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2023-10-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanofabrication\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.37819/nanofab.8.336\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"NANOSCIENCE & NANOTECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanofabrication","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37819/nanofab.8.336","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"NANOSCIENCE & NANOTECHNOLOGY","Score":null,"Total":0}
引用次数: 0
摘要
加入S-g-C3N4后,其电化学性能得到增强。硫的引入促进了复合材料内部高导电性网络的形成,实现了有效的电荷转移和提高了比电容。g-C3N4基质作为支持网络,控制了CuNPs的积累,并在电化学循环过程中提供了稳定性。优化后的S-g-C3N4/CuNPs复合材料具有优异的电化学性能、较高的比电容和更强的循环稳定性。本研究采用一种简便、可扩展的合成方法,在GCE上制备了S-g-C3N4/CuNPs复合材料。利用不同的光学和显微技术对所得复合材料进行了表征。通过循环伏安法(CV)和恒流充放电(GCD)等技术对纳米复合材料的电化学性能进行了评价。在0.5 a /g电流密度下,S-g-C3N4/CuNPs纳米复合材料的比电容达到1944.18 F/g,具有良好的循环稳定性。合成的复合材料表现出优异的电化学性能,使其成为需要高功率密度、长循环寿命和稳定性能的储能应用的有利人选。
Incorporation of sulfur with graphitic carbon nitride into copper nanoparticles toward supercapacitor application
The incorporation of S-g-C3N4 into CuNPs resulted in enhanced electrochemical performance. The introduction of sulfur facilitated the formation of a highly conductive network within the composite material, enabling effective charge transfer and improved specific capacitance. The g-C3N4 matrix served as a support network, controlling the accumulation of CuNPs and delivering stability during electrochemical cycling. The optimized S-g-C3N4/CuNPs composite showed superior electrochemical performance, high specific capacitance, and enhanced cycling stability. In this study, a facile and scalable synthesis method was employed to fabricate S-g-C3N4/CuNPs composite materials on GCE. The resulting composites were characterized using different optical and microscopic techniques. The electrochemical performance of the nanocomposites was assessed via using different techniques such as cyclic voltammetry (CV), and galvanostatic charge-discharge (GCD) techniques. The S-g-C3N4/CuNPs nanocomposite exhibited excellent electrochemical properties with a specific capacitance of 1944.18 F/g at a current density of 0.5 A/g and excellent cycling stability. The resultant composite material exhibits excellent electrochemical performance, making it an advantageous nominee for energy storage applications needing high power density, extended cycling life, and steadfast performance.