用酚类化合物水萃取物超滤的方法对湿橄榄渣进行绿色管理。

Carmen M. Sánchez-Arévalo, María Cinta Vincent-Vela, Silvia Álvarez-Blanco
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引用次数: 1

摘要

湿橄榄渣是橄榄磨坊生产的主要副产品。为了促进橄榄产业的循环经济,从湿橄榄渣中回收有趣的化合物进行了评估。为此,一种先前优化的固液萃取法,仅用水作为萃取剂,首次应用于湿橄榄渣。然后,开发了一种超滤工艺来处理所得到的提取物。研究了几种膜(来自Microdyn Nadir的UP005、UH030、UH050和UP150)在大范围内的横流速度(1.5-3.5 m/s)和跨膜压力(0.75-5.5 bar)。通过LC-ESI-QToF-MS对超滤流的全面表征,可以描述29种酚类化合物的去除过程。在超滤过程中也观察到一些吸附过程。UP005和UH030膜的渗透通量和截留值令人满意。两种膜都有效地保留了大部分的总固体、化学需氧量和颜色。相反,酚类化合物是在超滤渗透物中获得的,它构成了抗氧化分子的来源,在化妆品、制药和营养保健品中有应用。
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Green management of wet olive pomace by means of ultrafiltration of an aqueous extract of phenolic compounds.
Wet olive pomace is a major by-product generated by olive mills. To contribute to the circular economy of the olive industry, the recovery of interesting compounds from wet olive pomace was assessed. To that end, a previously optimized solid-liquid extraction, only employing water as the extractant, was first applied to the wet olive pomace. Afterwards, an ultrafiltration process to treat the obtained extract was developed. Several membranes (UP005, UH030, UH050, and UP150, from Microdyn Nadir) were studied, in a wide range of cross-flow velocities (1.5-3.5 m/s) and transmembrane pressures (0.75-5.5 bar). By a thorough characterization of the ultrafiltration streams by LC-ESI-QToF-MS, it was possible to describe the evolution of the rejection of 29 phenolic compounds. Some adsorption processes were also observed in the ultrafiltration process. The UP005 and UH030 membranes displayed satisfactory values of permeate flux and rejection. Both membranes efficiently retained a high fraction of the total solids, chemical oxygen demand, and color. On the contrary, the phenolic compounds were obtained in the ultrafiltration permeate, which constitutes a source of antioxidant molecules with applications in cosmetics, pharmacy, and nutraceutics.
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