Trinh Nguyen Thi, Phuoc Cao Van, Kirakosyan Artavazd, Chanyong Hwang, Jihoon Choi, Hyojin Kim, Jong-Ryul Jeong
{"title":"热处理温度对ε-Fe<SUB>2</SUB> 0 <SUB>3</SUB>形成的影响SiO<SUB>2</SUB>","authors":"Trinh Nguyen Thi, Phuoc Cao Van, Kirakosyan Artavazd, Chanyong Hwang, Jihoon Choi, Hyojin Kim, Jong-Ryul Jeong","doi":"10.4283/jmag.2023.28.3.239","DOIUrl":null,"url":null,"abstract":"ε-FeSUB2/SUBOSUB3/SUB has received attention with particular interest because of its large coercive field at room temperature, high-frequency millimeter-wave absorption, and the coupling of its magnetic and dielectric properties. This work investigated the effect of heat treatment on the formation of ε-FeSUB2/SUBOSUB3/SUB/SiOSUB2/SUB composites fabricated using reverse-micelle and sol-gel methods. The heating process was performed at various temperatures to figure out the optimal conditions for acquisition of the ε-FeSUB2/SUBOSUB3/SUB phase, which exhibits the largest coercive field among the Fe oxides. The sample treated at 1,075 °C had the highest percentage of ε-FeSUB2/SUBOSUB3/SUB phase, with a coercivity (HC) of 21.57 kOe measured at room temperature that reached a maximum of 23.7 kOe at 230 K. The measurement of the magnetization-temperature (M-T) curve for this sample also reveals the characteristic magnetic transition associated with ε-FeSUB2/SUBOSUB3/SUB within the temperature range of 40-150 K. The crystal structure of ε-FeSUB2/SUBOSUB3/SUB was confirmed using X-ray powder diffraction. Transmission electron micrographs revealed a broad size distribution of iron oxide nanoparticles ranging from 12 to 22 nm. The findings indicate that ε-FeSUB2/SUBOSUB3/SUB is a promising candidate with high electromagnetic-wave absorption capacity that is appropriate for high-speed wireless communication applications.","PeriodicalId":16147,"journal":{"name":"Journal of Magnetics","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Heat-treatment Temperature on the Formation of ε-Fe<SUB>2</SUB>O<SUB>3</SUB> Nanoparticles Encapsulated by SiO<SUB>2</SUB>\",\"authors\":\"Trinh Nguyen Thi, Phuoc Cao Van, Kirakosyan Artavazd, Chanyong Hwang, Jihoon Choi, Hyojin Kim, Jong-Ryul Jeong\",\"doi\":\"10.4283/jmag.2023.28.3.239\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ε-FeSUB2/SUBOSUB3/SUB has received attention with particular interest because of its large coercive field at room temperature, high-frequency millimeter-wave absorption, and the coupling of its magnetic and dielectric properties. This work investigated the effect of heat treatment on the formation of ε-FeSUB2/SUBOSUB3/SUB/SiOSUB2/SUB composites fabricated using reverse-micelle and sol-gel methods. The heating process was performed at various temperatures to figure out the optimal conditions for acquisition of the ε-FeSUB2/SUBOSUB3/SUB phase, which exhibits the largest coercive field among the Fe oxides. The sample treated at 1,075 °C had the highest percentage of ε-FeSUB2/SUBOSUB3/SUB phase, with a coercivity (HC) of 21.57 kOe measured at room temperature that reached a maximum of 23.7 kOe at 230 K. The measurement of the magnetization-temperature (M-T) curve for this sample also reveals the characteristic magnetic transition associated with ε-FeSUB2/SUBOSUB3/SUB within the temperature range of 40-150 K. The crystal structure of ε-FeSUB2/SUBOSUB3/SUB was confirmed using X-ray powder diffraction. Transmission electron micrographs revealed a broad size distribution of iron oxide nanoparticles ranging from 12 to 22 nm. The findings indicate that ε-FeSUB2/SUBOSUB3/SUB is a promising candidate with high electromagnetic-wave absorption capacity that is appropriate for high-speed wireless communication applications.\",\"PeriodicalId\":16147,\"journal\":{\"name\":\"Journal of Magnetics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2023-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Magnetics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4283/jmag.2023.28.3.239\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Magnetics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4283/jmag.2023.28.3.239","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of Heat-treatment Temperature on the Formation of ε-Fe<SUB>2</SUB>O<SUB>3</SUB> Nanoparticles Encapsulated by SiO<SUB>2</SUB>
ε-FeSUB2/SUBOSUB3/SUB has received attention with particular interest because of its large coercive field at room temperature, high-frequency millimeter-wave absorption, and the coupling of its magnetic and dielectric properties. This work investigated the effect of heat treatment on the formation of ε-FeSUB2/SUBOSUB3/SUB/SiOSUB2/SUB composites fabricated using reverse-micelle and sol-gel methods. The heating process was performed at various temperatures to figure out the optimal conditions for acquisition of the ε-FeSUB2/SUBOSUB3/SUB phase, which exhibits the largest coercive field among the Fe oxides. The sample treated at 1,075 °C had the highest percentage of ε-FeSUB2/SUBOSUB3/SUB phase, with a coercivity (HC) of 21.57 kOe measured at room temperature that reached a maximum of 23.7 kOe at 230 K. The measurement of the magnetization-temperature (M-T) curve for this sample also reveals the characteristic magnetic transition associated with ε-FeSUB2/SUBOSUB3/SUB within the temperature range of 40-150 K. The crystal structure of ε-FeSUB2/SUBOSUB3/SUB was confirmed using X-ray powder diffraction. Transmission electron micrographs revealed a broad size distribution of iron oxide nanoparticles ranging from 12 to 22 nm. The findings indicate that ε-FeSUB2/SUBOSUB3/SUB is a promising candidate with high electromagnetic-wave absorption capacity that is appropriate for high-speed wireless communication applications.
期刊介绍:
The JOURNAL OF MAGNETICS provides a forum for the discussion of original papers covering the magnetic theory, magnetic materials and their properties, magnetic recording materials and technology, spin electronics, and measurements and applications. The journal covers research papers, review letters, and notes.