壳聚糖/MoS2/GO膜催化降解有机污染物

Delal E. Al Momani, Fathima Arshad, Linda Zou
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引用次数: 0

摘要

在壳聚糖聚合物基体中掺入二硫化钼和氧化石墨烯制备了纳米复合膜。聚合物与纳米材料的比例越高,CMG2膜的多孔性越好。对比两种膜的性能,不含纳米材料的对照膜对有机物的去除率最低,而两种纳米复合膜的去除率均达到95-100%。CMG2对MO溶液的TOC去除率也达到100%,而CMG1对TOC的去除率较低。二硫化钼纳米颗粒对有机物的降解具有催化作用。氧化石墨烯纳米片还引入了更大的负电荷,以增强对有机污染物的分离和排斥。此外,CMG2在每个过滤周期的处理动力学也比CMG1快。这是由于其较高的孔隙度有助于更好地接触二硫化钼纳米材料,因为染料分子与催化位点相互作用。壳聚糖/二硫化钼/氧化石墨烯膜是一种很有前途的膜基溶液,可用于水和废水处理中有机污染物的高效催化降解。
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Chitosan/MoS2/GO membrane for catalytic degradation of organic contaminants
Nanocomposite membranes were fabricated by incorporating MoS2 and GO nanomaterials in the chitosan polymer matrix. The higher polymer to nanomaterial ratio resulted in more porous CMG2 membrane than CMG1 membrane. In comparison of the membranes’ performance, the control membrane without nanomaterials only had minimal removal of organic matter, whereas both nanocomposite membranes achieved 95-100% color removal. CMG2 also achieved 100% TOC removals of MO solutions whereas the TOC removal by CMG1 was less complete. The MoS2 nanoparticles induced catalytic effect to degradate organic matter. The GO nanosheets also introduced a more substantial negative charge to enhance the separation and rejection of organic contaminants. In addition, a faster treatment kinetics per filtration cycle was also displayed by CMG2 than that of CMG1. This was due to its higher posoristy facilitated better access to the MoS2 nanomaterials, for the dye molecules interacting with catalytic sites. Chitosan/MoS2/GO membrane could be a promising membrane-based solution for efficient catalytic degradation of organic contaminants in water and wastewater treatment.
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