纳米复合γ-三氧化铁(γ-Fe2O3)介导,绿色,无溶剂,一锅合成天然醋酸酯

IF 0.4 4区 化学 Q4 CHEMISTRY, ORGANIC INDIAN JOURNAL OF CHEMISTRY Pub Date : 2023-09-18 DOI:10.56042/ijc.v62i9.5358
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引用次数: 0

摘要

采用溶胶-凝胶法制备了不同结构的定向剂,合成了纳米复合氧化铁γ-Fe2O3。用XRD和FT-IR对合成的γ-Fe2O3进行了表征。利用这种纳米氧化铁催化剂合成了不同的天然乙酸酯,并用光谱方法对其进行了分析。考察了该催化剂对天然醋酸酯的绿色、无溶剂、一锅合成的催化活性。结果表明,以尿素为结构导向剂合成的γ-Fe2O3与其他方法合成的产物相比,乙酸转化率最高。
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Nanocomposite γ-ferric oxide (γ-Fe2O3) mediated, green, solvent free, one pot synthesis of naturally occurring acetate esters
Nanocomposite ferric oxide, γ-Fe2O3 has been synthesized using different structure directing agents by sol-gel method. The synthesized γ-Fe2O3 has been characterized by XRD and FT-IR. Using this nano-ferric oxide catalyst, different naturally occurring acetate esters have been synthesized and analyzed using spectroscopic methods. The catalytic activity of the catalyst has been investigated for the green, solvent free, one pot synthesis of naturally occurring acetate esters. It is observed that the γ-Fe2O3, synthesized by using urea as structure directing agent shows the highest percent conversion of acetic acid as compared to those synthesized via other methods.
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