合金元素对碳纤维-石墨薄片/铜复合材料热物理性能的影响

Youming Chen, Tongle Liu, Guodong Miao, Junchen Huang, Bing Yang, Qian Liu
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摘要

采用粉末冶金法制备了碳纤维-石墨片/铜复合材料。研究了合金元素Ti和Zr对复合材料性能的影响,并探讨了Zr含量对复合材料相结构和导热性能的影响。结果表明,与含Ti的复合材料相比,含Zr的复合材料具有更好的抗弯强度和导热性。当碳纤维体积分数为2%时,在铜基体中加入2 wt%的Zr,复合界面处的碳化物层均匀,厚度为0.36 μm。复合材料的导热系数高达597.5 W/(m∙K)。碳纤维与合金基体的协同作用增强了复合材料的力学性能,复合材料的抗弯强度达到150.5 MPa,比未添加碳纤维的复合材料提高了58.3%。进一步探讨了碳纤维对复合材料力学性能的增强机理。采用声学失配模型(Acoustic Mismatch Model, AMM)结合Digimat软件的MF模块对多相复合材料的导热系数进行了有效预测,并分析了Ti或Zr元素对复合材料导热系数的影响。
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The effect of alloying element on the thermophysical properties of carbon fiber-graphite flakes/copper composites
In this study, carbon fiber-graphite flake/copper composites were prepared by powder metallurgy. The impact of the alloying elements Ti and Zr on the composites’ properties was investigated, and the influence of varying Zr contents on the phase structure and thermal conductivity of the composites was also explored. The results indicate that composites containing Zr exhibit better flexural strength and thermal conductivity compared to those containing Ti. When the volume fraction of carbon fiber is 2% and 2 wt% Zr is added to copper matrix, the carbide layer at the composite interface is uniform and has a thickness of 0.36 μm. The thermal conductivity of the composite material is up to 597.5 W/(m∙K). The mechanical properties of the composites are enhanced by the synergistic effect of adding carbon fiber and alloying matrix and the composite shows a remarkable flexural strength of 150.5 MPa, which is 58.3% higher compared to composites without carbon fiber. Furthermore, the strengthening mechanism of carbon fiber on the mechanical properties of the composites was examined. The thermal conductivity of the multiphase composites was effectively predicted using the Acoustic Mismatch Model (AMM) combined with the MF module of Digimat software, and the impact of Ti or Zr elements on the composites’ thermal conductivity was analyzed.
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