几种热带木材的理化、结构和形态特征及其在木材工业中的应用

Jude I. Duruaku, Patrick A. C. Okoye, Nkechi H. Okoye, Joseph O. Nwadiogbu, Valentine I. Onwukeme, Rosemary U. Arinze
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引用次数: 1

摘要

本文研究并量化了四种热带木材的物理化学、结构和形态特性,作为木塑工业中可能利用的前驱原料。木材样品的物理化学性质,如体积和密度、水分含量、25°C下的吸水能力、挥发性含量、固定碳、灰分含量、α纤维素、半纤维素、木质素和萃取物含量,采用欧洲标准化委员会(CEN/TS)和美国材料测试协会(ASTM)标准等标准方法测定。利用傅里叶红外光谱(FTIR)和扫描电子显微镜(SEM)对样品的结构和形态进行了表征。结果表明:各树种木材的容重值为:阔阔阔臂藓(Brachystegia eurycoma, W3) 0.34 g/cm3 ~粗红叶藓(Erythrophleum suaveolens, W2) 0.47 g/cm3,其他树种核仁(Nuclea diderichii, W1)和非洲Prosopis africana (Prosopis africana, W4)容重均为0.40 g/cm3。水分含量以W2最高(8.38%),狄氏核桃仁最低(6.52%)。所研究木材的吸水能力与木材的纤维素组成有关,其顺序为:W3 > W1 > W4 > W2。FTIR结果表明,在1731 cm-1处,W2和W3比其他树种的木质素含量更高,其谱带略突出,宽度略宽,这与这些树种的整体纤维素含量较高一致,而W2和W4的木质素含量比W1和W3高。木粉样品的SEM显微图表明,木粉表面粗糙且不均匀,晶粒不规则,颗粒呈砖状。木材化学成分的双向方差分析(ANOVA)表明,树种间木材化学成分的差异无统计学意义,p值(0.852)大于临界水平(α = 0.05)。
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An Evaluation of the Physicochemical, Structural and Morphological Properties of Selected Tropical Wood Species for Possible Utilization in the Wood Industry
This work investigated and quantified the physicochemical, structural and morphological properties of four (4) tropical timbers as precursor raw materials for possible utilization in the wood plastic industry. The physicochemical properties of the wood samples such as the bulk and tapped density, moisture content, water absorption capacity at 25°C, volatile content, fixed carbon, ash content, alpha cellulose, hemicellulose, lignin, and extractives contents were determined using standard methods like the European Committee for Standardization and (CEN/TS) and the American Society for Testing Materials (ASTM) standards. The structural and morphological properties of the samples were examined with Fourier Infrared Transform (FTIR) spectroscopy and scanning electron microscope (SEM). Results indicated that the bulk density values of the timbers ranged from 0.34 g/cm3 in Brachystegia eurycoma (W3) to 0.47 g/cm3 in Erythrophleum suaveolens (W2), with the other timbers, Nuclea diderichii (W1) and Prosopis africana (W4) having the same bulk density of 0.40 g/cm3. With respect to their moisture content, W2 had the highest value (8.38%) while Nauclea diderrichii had the lowest value (6.52%). The water absorption capacities of the woods studied correlated with the cellulose composition of wood in the order of: W3 > W1 > W4 > W2. The FTIR results showed that W2 and W3 presented a slightly more prominent and broader band than the other woods at 1731 cm-1, in agreement with the higher holocellulose content of these species, while W2 and W4 presented the most prominent peaks indicating higher lignin content than W1 and W3. The SEM micrographs of the wood flour samples investigated indicated that the surfaces of the woods were rough and heterogeneous with irregular crystal and brick shaped particles. A two-way analysis of variance (ANOVA) carried out with respect to the chemical composition of the wood samples indicated that there was no statistically significant variation in the wood chemical composition between species as the p-value (0.852) obtained was greater than the critical level of α = 0.05.
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