Feng Jiang, Junling Yu, Guo Feng, Tao Wang, Xiaojun Zhang, Quan Zhang, Rongchi Zhang, Qian Wu, Qing Hu, Yun Yu, Jianmin Liu
{"title":"(Cr,V)-ZrSiO4宝石绿颜料的合成及其近红外反射性能","authors":"Feng Jiang, Junling Yu, Guo Feng, Tao Wang, Xiaojun Zhang, Quan Zhang, Rongchi Zhang, Qian Wu, Qing Hu, Yun Yu, Jianmin Liu","doi":"10.2298/pac2303295j","DOIUrl":null,"url":null,"abstract":"Novel (Cr,V)-ZrSiO4 jewel green pigments were synthesized by in situ mineralization at 900?C. The effects of Cr/Si molar ratio were investigated via DTA-TG, XRD, FE-SEM, TEM, UV-Vis-NIR, colorimeter and etc. The obtained results referred that the colour of pigment exhibits blue to jewel green, and then to dark green as the Cr/Si molar ratio increases from 0 to 0.4. When the Cr/Si molar ratio is 0.2, the (Cr,V)-ZrSiO4 pigment exhibits a jewel green hue (L* = 56.69, a* = ?18.52, b* = ?9.28), showing good rendering performance. In addition, the obtained pigment shows good thermal stability in the base glaze synthesized at 1200?C and near-infrared reflection performance. The results of this study show great potential for using the pigments for heat insulation.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"5 1","pages":"0"},"PeriodicalIF":0.9000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and near-infrared reflection performance of (Cr,V)-ZrSiO4 jewel green pigments\",\"authors\":\"Feng Jiang, Junling Yu, Guo Feng, Tao Wang, Xiaojun Zhang, Quan Zhang, Rongchi Zhang, Qian Wu, Qing Hu, Yun Yu, Jianmin Liu\",\"doi\":\"10.2298/pac2303295j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Novel (Cr,V)-ZrSiO4 jewel green pigments were synthesized by in situ mineralization at 900?C. The effects of Cr/Si molar ratio were investigated via DTA-TG, XRD, FE-SEM, TEM, UV-Vis-NIR, colorimeter and etc. The obtained results referred that the colour of pigment exhibits blue to jewel green, and then to dark green as the Cr/Si molar ratio increases from 0 to 0.4. When the Cr/Si molar ratio is 0.2, the (Cr,V)-ZrSiO4 pigment exhibits a jewel green hue (L* = 56.69, a* = ?18.52, b* = ?9.28), showing good rendering performance. In addition, the obtained pigment shows good thermal stability in the base glaze synthesized at 1200?C and near-infrared reflection performance. The results of this study show great potential for using the pigments for heat insulation.\",\"PeriodicalId\":20596,\"journal\":{\"name\":\"Processing and Application of Ceramics\",\"volume\":\"5 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Processing and Application of Ceramics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2298/pac2303295j\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Processing and Application of Ceramics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2298/pac2303295j","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Synthesis and near-infrared reflection performance of (Cr,V)-ZrSiO4 jewel green pigments
Novel (Cr,V)-ZrSiO4 jewel green pigments were synthesized by in situ mineralization at 900?C. The effects of Cr/Si molar ratio were investigated via DTA-TG, XRD, FE-SEM, TEM, UV-Vis-NIR, colorimeter and etc. The obtained results referred that the colour of pigment exhibits blue to jewel green, and then to dark green as the Cr/Si molar ratio increases from 0 to 0.4. When the Cr/Si molar ratio is 0.2, the (Cr,V)-ZrSiO4 pigment exhibits a jewel green hue (L* = 56.69, a* = ?18.52, b* = ?9.28), showing good rendering performance. In addition, the obtained pigment shows good thermal stability in the base glaze synthesized at 1200?C and near-infrared reflection performance. The results of this study show great potential for using the pigments for heat insulation.
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