堇青石基陶瓷复合材料的力学和腐蚀性能研究

IF 0.9 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Processing and Application of Ceramics Pub Date : 2023-01-01 DOI:10.2298/pac2303271p
Tuğba Parlak, Ediz Ercenk, Abdülkadir Akyol, Sevcan Ceylan, Ayşe Demirkiran
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引用次数: 0

摘要

MgO-Al2O3-SiO2 (MAS)体系的基本相之一堇青石的化学式为2MgO?2 Al2O3 ?5二氧化矽。因此,堇青石一般采用天然原料液相烧结法生产。本研究以天然沸石为原料,在低至1250℃的温度下,经济地制备了致密堇青石和堇青石基/ZrO2陶瓷复合材料。用XRD进行物相分析,用SEM/FESEM进行微观结构分析。还测试了ZrSiO4晶体在堇青石基体中的热盐腐蚀行为。结果表明,ZrO2的加入降低了合金的平均晶粒尺寸,提高了合金的耐磨性和耐腐蚀性。测定了堇青石基/ZrO2陶瓷复合材料的密度、孔隙率、硬度、抗弯强度和磨损性能。此外,测定了无氧化锆试样、含氧化锆量为10 wt.%和20 wt.%试样的硬度值分别为11.29、12.60和12.91GPa,比磨损率为5.097 ?10 ?3、6.302 ?10 ?6和3.393 ?10 ?分别是7mm3 /Nm。氧化锆的加入提高了合金的硬度,改变了合金的耐磨性。
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An investigation about the mechanical and corrosion properties of cordierite based ceramic composites
One of the essential phases in the MgO-Al2O3-SiO2 (MAS) system, cordierite, has the chemical formula 2MgO? 2 Al2O3 ? 5 SiO2. Therefore, cordierite is generally produced from natural raw materials by liquid phase sintering. In this study, dense cordierite and cordierite-based/ZrO2 ceramic composites were produced economically from natural zeolite at a temperature as low as 1250 ?C. Phase analyses with XRD and microstructure examinations with SEM/FESEM were performed. The hot salt corrosion behaviour of ZrSiO4 crystals in a cordierite matrix was also tested. It was determined that the addition of ZrO2 to reduce the average grain size had a positive effect on wear and corrosion resistance. Density, porosity, hardness, flexural strength and wear behaviour of the cordierite-based/ZrO2 ceramic composites were determined. In addition, the hardness values of the zirconia free sample, the samples containing 10 and 20 wt.% zirconia were measured as 11.29, 12.60 and 12.91GPa, respectively, while the specific wear rates were identified as 5.097 ? 10?3, 6.302 ? 10?6 and 3.393 ? 10?7 mm3/Nm, respectively. The hardness increased and the wear resistance changed with the addition of zirconia.
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来源期刊
Processing and Application of Ceramics
Processing and Application of Ceramics MATERIALS SCIENCE, CERAMICS-
CiteScore
1.90
自引率
9.10%
发文量
14
审稿时长
10 weeks
期刊介绍: Information not localized
期刊最新文献
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