C-C 和 C-O 多键电化学还原转化的最新进展

IF 2.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Israel Journal of Chemistry Pub Date : 2023-11-08 DOI:10.1002/ijch.202300102
Atreyee Halder, Kingshuk Mahanty, Debabrata Maiti, Dr. Suman De Sarkar
{"title":"C-C 和 C-O 多键电化学还原转化的最新进展","authors":"Atreyee Halder,&nbsp;Kingshuk Mahanty,&nbsp;Debabrata Maiti,&nbsp;Dr. Suman De Sarkar","doi":"10.1002/ijch.202300102","DOIUrl":null,"url":null,"abstract":"<p>In recent decades, electro-organic synthesis is indubitably emerging as a cornerstone of modern organic chemistry. Electrochemical organic transformations especially reduction reactions have made massive advancements in the last few years because of their sustainable and environ-friendly nature. Electro-reductive protocols can be used as a promising substitute for conventional reductants by expelling the requirement of the stoichiometric amount of metal reductants. The major challenges for these electro-reductive reactions are primarily the use of a sacrificial electrode and divided cells. These limitations can be resolved through smart reaction planning by employing cheap sacrificial reagents or paired electrolysis without compromising the sustainable viewpoint. Considering the rapid enhancement in this field, imparting an intangible understanding of this evolving area is essential and substantial. In this review, we portrayed the electrochemical reductive transformations of C−C and C−O bonds after 2015 along with detailed mechanistic insights.</p>","PeriodicalId":14686,"journal":{"name":"Israel Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":2.3000,"publicationDate":"2023-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent Advances in Electrochemical Reductive Transformation of C−C and C−O Multiple Bonds\",\"authors\":\"Atreyee Halder,&nbsp;Kingshuk Mahanty,&nbsp;Debabrata Maiti,&nbsp;Dr. Suman De Sarkar\",\"doi\":\"10.1002/ijch.202300102\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In recent decades, electro-organic synthesis is indubitably emerging as a cornerstone of modern organic chemistry. Electrochemical organic transformations especially reduction reactions have made massive advancements in the last few years because of their sustainable and environ-friendly nature. Electro-reductive protocols can be used as a promising substitute for conventional reductants by expelling the requirement of the stoichiometric amount of metal reductants. The major challenges for these electro-reductive reactions are primarily the use of a sacrificial electrode and divided cells. These limitations can be resolved through smart reaction planning by employing cheap sacrificial reagents or paired electrolysis without compromising the sustainable viewpoint. Considering the rapid enhancement in this field, imparting an intangible understanding of this evolving area is essential and substantial. In this review, we portrayed the electrochemical reductive transformations of C−C and C−O bonds after 2015 along with detailed mechanistic insights.</p>\",\"PeriodicalId\":14686,\"journal\":{\"name\":\"Israel Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2023-11-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Israel Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ijch.202300102\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Israel Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ijch.202300102","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

近几十年来,电有机合成已无可争议地成为现代有机化学的基石。电化学有机转化,尤其是还原反应,因其可持续和环保的特性,在过去几年中取得了巨大的进步。电还原反应不需要等量的金属还原剂,因此可以替代传统的还原剂。这些电还原反应面临的主要挑战是使用牺牲电极和分隔电池。这些限制可以通过采用廉价的牺牲试剂或配对电解进行智能反应规划来解决,而不会影响可持续观点。考虑到这一领域的快速发展,传授对这一不断发展的领域的无形理解至关重要。在这篇综述中,我们描绘了 2015 年之后 C-C 和 C-O 键的电化学还原转化以及详细的机理见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Recent Advances in Electrochemical Reductive Transformation of C−C and C−O Multiple Bonds

In recent decades, electro-organic synthesis is indubitably emerging as a cornerstone of modern organic chemistry. Electrochemical organic transformations especially reduction reactions have made massive advancements in the last few years because of their sustainable and environ-friendly nature. Electro-reductive protocols can be used as a promising substitute for conventional reductants by expelling the requirement of the stoichiometric amount of metal reductants. The major challenges for these electro-reductive reactions are primarily the use of a sacrificial electrode and divided cells. These limitations can be resolved through smart reaction planning by employing cheap sacrificial reagents or paired electrolysis without compromising the sustainable viewpoint. Considering the rapid enhancement in this field, imparting an intangible understanding of this evolving area is essential and substantial. In this review, we portrayed the electrochemical reductive transformations of C−C and C−O bonds after 2015 along with detailed mechanistic insights.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Israel Journal of Chemistry
Israel Journal of Chemistry 化学-化学综合
CiteScore
6.20
自引率
0.00%
发文量
62
审稿时长
6-12 weeks
期刊介绍: The fledgling State of Israel began to publish its scientific activity in 1951 under the general heading of Bulletin of the Research Council of Israel, which quickly split into sections to accommodate various fields in the growing academic community. In 1963, the Bulletin ceased publication and independent journals were born, with Section A becoming the new Israel Journal of Chemistry. The Israel Journal of Chemistry is the official journal of the Israel Chemical Society. Effective from Volume 50 (2010) it is published by Wiley-VCH. The Israel Journal of Chemistry is an international and peer-reviewed publication forum for Special Issues on timely research topics in all fields of chemistry: from biochemistry through organic and inorganic chemistry to polymer, physical and theoretical chemistry, including all interdisciplinary topics. Each topical issue is edited by one or several Guest Editors and primarily contains invited Review articles. Communications and Full Papers may be published occasionally, if they fit with the quality standards of the journal. The publication language is English and the journal is published twelve times a year.
期刊最新文献
Cover Picture: (Isr. J. Chem. 8-9/2024) Special Issue on RNA-Based Catalysts that Revolutionized the Discovery of Bioactive Peptides Hexagonal and Trigonal Quasiperiodic Tilings Breaking the Degeneracy of Sense Codons – How Far Can We Go? Cover Picture: (Isr. J. Chem. 6-7/2024)
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1