木结构阻燃浸渍剂的有效性

Ilya Fedotov, Andrey Sivenkov, Yuri Naganovsky
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摘要

本文考虑了根据GOST 53292-2009的火灾暴露法和热分析方法(热重法、差分热重法、导数热分析)对各种阻燃剂的阻燃效果进行评价的结果。根据防火结果表面应用的阻燃剂为350 ~ 550 kg/m2, I类或II类阻燃剂 提供效率(质量损失从8.67 - 25%)。结果表明,组阻燃效果并不能实际反映阻燃剂的阻燃作用机理的性质和实现程度,其对木材热转化特性的影响能力。研究表明,阻燃剂的种类、化学成分组成和阻燃作用机理不同程度地影响木材热氧化分解的主要阶段。所得结果可用于评价防火在降低炭化过程强度和预测木材阴燃(无焰)燃烧强度方面的有效性。经检测,发现与消费有关
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THE EFFECTIVENESS OF FLAME RETARDANT IMPREGNATING COMPOUNDS FOR WOODEN STRUCTURES
The article considers the results of evaluating the flame retardant effectiveness of various flame retardants by the method of fire exposure according to GOST 53292–2009 and by methods of thermal analysis (thermogravimetry, differential thermogravimetry, derivative thermal analysis). According to the results of fire of surface application of flame retardants from 350 to 550 kg/m2, group I or II of flame retardant efficiency is provided (mass loss from 8,67 to 25 %). It is shown that the group of flame-retardant effectiveness does not actually reflect the nature and degree of realization of the mechanism of flame retardant action of flame retardants, their ability to influence the features of thermal transformations of wood. It has been established that the type of flame retardant, its chemical component composition and the mechanism of flame retardant action to varying degrees affect the main stages of thermal oxidative decomposition of wood. The results obtained can be used to evaluate the effectiveness of fire protection in reducing the intensity of the charring process and predicting the intensity of smoldering (flameless) combustion of wood. tests, it was found that with the consumption
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