五甲基环-戊二烯铑配合物催化NADH再生体系中水溶性锌卟啉的结构效应

IF 3.3 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Bulletin of the Chemical Society of Japan Pub Date : 2023-09-14 DOI:10.1246/bcsj.20230137

Mika Takeuchi, Yutaka Amao

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引用次数: 0

摘要

研究了水溶性卟啉锌(ZnP)离子取代基(4-磺基苯基、4-羧基苯基、4-甲基吡啶基和4-N,N,N-三甲基氨基苯基)对三乙乙醇胺、ZnP和铑配合物[Cp*Rh(bpy)(H2O)]2+ (Cp* =五甲基环戊二烯基，bpy = 2,2′-联吡啶基)体系可见光再生NADH的影响，为与多种氧化还原酶的杂交提供重要指导。研究了水溶性卟啉锌离子取代基(4-磺基苯基、4-羧基苯基、4-甲基吡啶基和4-N,N,N-三甲氨基苯基)对三乙乙醇胺、水溶性卟啉锌和铑配合物[Cp*Rh(bpy)(H2O)]2+ (Cp* =五甲基环戊二烯基，bpy = 2,2′-联吡啶基)体系可见光再生NADH的影响。

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Structural effect of water-soluble zinc porphyrins in visible-light driven NADH regeneration system catalyzed by rhodium pentamethylcyclo-pentadienyl complex

The effect of ionic substituents (4-sulfonatophenyl, 4-carboxyphenyl, 4-methylpyridyl, and 4-N,N,N-trimethylaminophenyl-groups) of water-soluble zinc porphyrin (ZnP) on the visible light-driven NADH regeneration by the system of triethanolamine, ZnP, and rhodium complex [Cp*Rh(bpy)(H2O)]2+ (Cp* = pentamethylcyclopentadienyl, bpy = 2,2′-bipyridyl) was studied to provide significant guidance for hybridization with a wide range of oxidoreductases. The effect of ionic substituents (4-sulfonatophenyl, 4-carboxyphenyl, 4-methylpyridyl, and 4-N,N,N-trimethylaminophenyl-groups) of water-soluble zinc porphyrin on the visible light-driven NADH regeneration by the system of triethanolamine, water-soluble zinc porphyrin, and rhodium complex [Cp*Rh(bpy)(H2O)]2+ (Cp* = pentamethylcyclopentadienyl, bpy = 2,2′-bipyridyl) was demonstrated.

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来源期刊

Bulletin of the Chemical Society of Japan 化学-化学综合

CiteScore

6.40

自引率

5.00%

发文量

194

审稿时长

3-8 weeks

期刊介绍： The Bulletin of the Chemical Society of Japan (BCSJ) is devoted to the publication of scientific research papers in the fields of Theoretical and Physical Chemistry, Analytical and Inorganic Chemistry, Organic and Biological Chemistry, and Applied and Materials Chemistry. BCSJ appears as a monthly journal online and in advance with three kinds of papers (Accounts, Articles, and Short Articles) describing original research. The purpose of BCSJ is to select and publish the most important papers with the broadest significance to the chemistry community in general. The Chemical Society of Japan hopes all visitors will notice the usefulness of our journal and the abundance of topics, and welcomes more submissions from scientists all over the world.