钒酸钴纳米复合材料在亚甲基蓝染料上的吸附行为研究

Pub Date : 2023-01-01 DOI:10.56042/ijpap.v61i9.3521
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引用次数: 0

摘要

采用低温水热法成功合成了(α, β)-CoV3O8/V4O7纳米复合材料。通过粉末x射线衍射、傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和x射线能量色散光谱(EDX)分析表征了这些纳米复合材料的结构特性。合成的纳米复合材料的晶粒尺寸约为3.72 nm, SEM成像显示为聚集的不规则矩形纳米复合材料。研究了吸附动力学和等温线,结果表明吸附符合拟二级动力学模型和Langmuir等温线。研究了(α, β)-CoV3O8/V4O7纳米复合材料在不同染料浓度下对亚甲基蓝染料的吸附性能。20 μM的亚甲基蓝水溶液在5分钟内具有高达95%的吸附效率。
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Investigating Adsorption Behaviour of Cobalt Vanadate Nanocomposites on Methylene Blue Dye
(α, β)-CoV3O8/V4O7 nanocomposites have been successfully synthesized through a facile hydrothermal method at low temperature. The structural properties of these nanocomposites are characterized via Powder X-ray diffraction, Fourier Transform Infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), and X-ray energy dispersive spectroscopy (EDX) analysis. Synthesized nanocomposites were determined to have an approximate crystalline size of 3.72 nm, and SEM imaging exhibited aggregated irregular rectangular shaped nanocomposites. Adsorption kinetics and isotherms were examined, and the outcomes showed that the adsorption followed pseudo-second-order kinetic model and Langmuir isotherm. Adsorption of methylene blue dye was investigated using (α, β)-CoV3O8/V4O7 nanocomposites at varying concentrations of the dye. 20 μM aqueous solution of methylene blue was found to have a high adsorption efficiency of almost 95% in 5 minutes.
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