采用双管换热器的液氢加氢站低温冷能回收

IF 1.9 4区 工程技术 Q4 ENERGY & FUELS Journal of Renewable and Sustainable Energy Pub Date : 2023-09-01 DOI:10.1063/5.0158028
Rongze Hu, Bin Yang, Cunyang Shi, Mingzhe Xue, Shaowei Zhu
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引用次数: 0

摘要

回收液氢(LH2)的低温冷能,在加氢前对高压氢气进行预冷,可以显著降低液氢加氢站的电量和能耗。现有的方法,如混合,需要连续低温泵运行,不适合各种操作条件。本文提出了一种利用双管换热器回收LH2低温冷能的新方法,该方法可以解耦压缩和加注过程,满足氢气分配器对低温冷能的波动需求。换热器结构设计采用集总参数法和温度分区法。通过二维轴对称旋流模型的数值模拟,验证了温度划分方法在高压低温氢气中应用的准确性。由于LH2温度过低,二次制冷剂二氯甲烷(CH2Cl2)存在结冰危险。根据内管外壁表面温度和CH2Cl2凝固点温度的比较,最佳防冻条件为选择外管公称直径为0.032 m, CH2Cl2质量流量不小于1.72 kg s−1。在不冻结的情况下,回收率可达75.39%以上。
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Cryogenic cold energy recovery in liquid hydrogen refueling station with double-pipe heat exchanger
Recovering the cryogenic cold energy of liquid hydrogen (LH2) for precooling high-pressure hydrogen gas before refueling can significantly reduce the electricity and energy consumption of liquid hydrogen refueling stations. Existing methods, such as blending, require continuous cryogenic pump operation and are not suitable for various operating conditions. This work proposes a novel method to recover LH2 cryogenic cold energy using a double-pipe heat exchanger, which can decouple the compression and refueling process and meet the fluctuating demand for the cryogenic cold energy required by the hydrogen dispenser. The lumped parameter method and temperature partition method were adopted to design the heat exchanger structure. Numerical simulations of a 2D axisymmetric swirl model were done to verify the accuracy of the temperature partition method applied to high-pressure cryogenic hydrogen. Due to the low temperature of LH2, the secondary refrigerant dichloromethane (CH2Cl2) risks freezing. Comparing the outer wall surface temperature of the inner pipe with the CH2Cl2 freezing point temperature, the optimal anti-freezing condition is that the outer pipe nominal diameter should be selected as 0.032 m and CH2Cl2 mass flow rate should be at least 1.72 kg s−1. Recovery efficiency can reach over 75.39% without freezing.
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来源期刊
Journal of Renewable and Sustainable Energy
Journal of Renewable and Sustainable Energy ENERGY & FUELS-ENERGY & FUELS
CiteScore
4.30
自引率
12.00%
发文量
122
审稿时长
4.2 months
期刊介绍: The Journal of Renewable and Sustainable Energy (JRSE) is an interdisciplinary, peer-reviewed journal covering all areas of renewable and sustainable energy relevant to the physical science and engineering communities. The interdisciplinary approach of the publication ensures that the editors draw from researchers worldwide in a diverse range of fields. Topics covered include: Renewable energy economics and policy Renewable energy resource assessment Solar energy: photovoltaics, solar thermal energy, solar energy for fuels Wind energy: wind farms, rotors and blades, on- and offshore wind conditions, aerodynamics, fluid dynamics Bioenergy: biofuels, biomass conversion, artificial photosynthesis Distributed energy generation: rooftop PV, distributed fuel cells, distributed wind, micro-hydrogen power generation Power distribution & systems modeling: power electronics and controls, smart grid Energy efficient buildings: smart windows, PV, wind, power management Energy conversion: flexoelectric, piezoelectric, thermoelectric, other technologies Energy storage: batteries, supercapacitors, hydrogen storage, other fuels Fuel cells: proton exchange membrane cells, solid oxide cells, hybrid fuel cells, other Marine and hydroelectric energy: dams, tides, waves, other Transportation: alternative vehicle technologies, plug-in technologies, other Geothermal energy
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