棕榈油和矿物油在绝缘纸、水分、低分子量酸和氧存在下的短期老化研究

IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pertanika Journal of Science and Technology Pub Date : 2023-10-03 DOI:10.47836/pjst.31.6.16
Muhammad Muzamil Mustam, Norhafiz Azis, Jasronita Jasni, Rasmina Halis, Mohd Aizam Talib, Robiah Yunus, Nurliyana Abdul Raof, Zaini Yaakub
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引用次数: 0

摘要

本研究介绍了在绝缘纸、水分、低分子量酸(LMA)和氧气存在下,精炼、漂白和脱臭棕榈油(RBDPO)和矿物油(MO)的短期老化研究。在140℃下进行7 d的老化实验。当纸张的水分在0.5%到3.5%之间变化时,油保持干燥。在老化开始之前,首先向油中注入0.2 g LMA和20 mbar的氧气压力。老化实验结束后进行了交流击穿电压(BDV)、油/纸抗拉强度、聚合度(DP)、热重分析和差示扫描量热分析(TGA-DSC)等分析。在LMA和氧气存在下老化后,RBDPO在所有水分水平下的AC BDV还原率都低于MO。在相同条件下,rbdpo浸渍纸的AC BDV也保持高于mo浸渍纸。rbdpo -浸渍纸在LMA和氧的存在下,即使在高水分条件下,也比基于DP和拉伸指数的mo -浸渍纸具有更高的抗老化性能。在LMA和氧气存在的情况下,所有RBDPO都比MO更耐老化。
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Short-term Ageing Study on the Palm Oil and Mineral Oil in the Presence of Insulation Paper, Moisture, Low Molecular Weight Acid, and Oxygen
This study presents the short-term ageing study on refined, bleached and deodorised palm oil (RBDPO) and mineral oil (MO) in the presence of insulation paper, moisture, low molecular weight acid (LMA) and oxygen. The ageing experiment was performed for 7 days at 140°C. The oil was maintained dried while the paper’s moisture was varied between 0.5% and 3.5%. In total, 0.2 g of LMA and 20 mbar of oxygen pressure were initially introduced in the oil before the ageing started. Several analyses were conducted after the ageing experiment, which include the AC breakdown voltage (BDV) oil/paper, tensile strength, degree of polymerization (DP) and thermogravimetric analysis and differential scanning calorimetry (TGA-DSC). After being subjected to ageing in the presence of LMA and oxygen, the reduction of AC BDV of RBDPO is lower than MO at all moisture levels. At the same condition, the AC BDV of RBDPO-impregnated paper also maintains higher than MO-impregnated paper. The RBDPO-impregnated paper, in the presence of LMA and oxygen, has higher resistance toward ageing than MO-impregnated paper based on DP and tensile index, even in high moisture. All RBDPO are more resistant to ageing than MO in the presence of LMA and oxygen based on the high onset temperatures of the TGA-DSC analysis.
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来源期刊
Pertanika Journal of Science and Technology
Pertanika Journal of Science and Technology MULTIDISCIPLINARY SCIENCES-
CiteScore
1.50
自引率
16.70%
发文量
178
期刊介绍: Pertanika Journal of Science and Technology aims to provide a forum for high quality research related to science and engineering research. Areas relevant to the scope of the journal include: bioinformatics, bioscience, biotechnology and bio-molecular sciences, chemistry, computer science, ecology, engineering, engineering design, environmental control and management, mathematics and statistics, medicine and health sciences, nanotechnology, physics, safety and emergency management, and related fields of study.
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