锌基金属-有机荧光传感框架材料的合成、机理及应用研究进展

Xiaojing Mao, Huachang Li, Jiemin Liu, Yehong Shi, Lijun Kuai
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引用次数: 0

摘要

随着越来越多的污染物对人类健康的威胁,开发灵敏、准确、快速的有害物质检测方法和传感材料是必要和必要的。金属-有机骨架是由无机金属离子或金属团簇与合适的有机配体组装而成的无机-有机杂化物。锌基MOFs (Zn-MOFs)由于其结构的多样性和无可比拟的稳定性,已成为mfs中最有应用前景的传感材料之一。然而,对Zn-MOFs的合成、设计、机理及应用等方面的系统综述却很少。本文综述了近十年来锌- mofs传感器识别的合成、设计方法、结构类型、发光机理及其在金属阳离子、阴离子、有机化合物等分析物中的应用。最后,对Zn-MOFs的未来发展方向进行了展望。
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Recent Progress in Synthesis, Mechanism and Applications of Zinc-Based Metal-Organic Frameworks for Fluorescent Sensing
As more and more pollutants threaten human health, it is necessary and essential to develop sensitive, accurate and rapid methods and sensory materials to detect harmful substance. Metal-organic frameworks (MOFs) are inorganic-organic hybrids assembled from inorganic metal ions or clusters and suitable organic ligands. Zinc-based MOFs (Zn-MOFs) have emerged as one of the most promising sensory material of MOFs for practical applications, and attracted significant attention due to structural diversity and incomparable stability properties. However, there are few reviews on systemic summary of synthesis design, mechanism and application of Zn-MOFs. In this review, we summarize the synthesis design methods, structure types and luminescence mechanism of Zn-MOFs sensor recognition in the past ten years and their applications in metal cations, anions, organic compounds and other analytes. Finally, we present a short conclusion, and look forward to the future development direction of Zn-MOFs.
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