土壤有机质的傅里叶变换红外光谱分析

Andrew J. Margenot, Sanjai J. Parikh, Francisco J. Calderón
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摘要

土壤有机质(SOM)的研究可以受益于傅里叶变换红外光谱的使用,这是一种补充传统分馏和提取方法的分析方法。本文综述了漫反射红外傅里叶变换(DRIFT)在中红外区域(MIR: 4000-400 cm−1)中的应用。本文综述了漂移光谱的两种不同应用:土壤有机质(1)表征和(2)定量。SOM的表征涉及构成有机物的官能团的定性到半定量测量,定量使用化学计量学来预测SOM的部分。提供了如何根据样本类型和研究问题进行方法决策的指导,以及对结果的解释。
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Fourier-transform infrared spectroscopy for soil organic matter analysis

The study of soil organic matter (SOM) can benefit from the use of Fourier-transform infrared spectroscopy, an analytical method that complements traditional fractionation and extraction methods. This review provides guidance on the use of diffuse reflectance infrared Fourier transform (DRIFT) in the mid-infrared region (MIR: 4000–400 cm−1). Two distinct applications of DRIFT spectroscopy are reviewed: soil organic matter (1) characterization and (2) quantification. Characterization of SOM involves the qualitative to semi-quantitative measurement of functional groups that constitute organic matter, and quantification employs chemometrics to predict fractions of SOM. Guidance on decision-making in how methods are conducted based on sample type and research question, and on interpretation of results are provided.

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