从含有Pt、Al、V、Co、Ni的一级胺的盐酸溶液中进行Re沉淀回收

Kazuya MATSUMOTO, Rio FUJII, Yuki HATA, Mitsutoshi JIKEI
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引用次数: 0

摘要

铼(Re)是一种重要的工业金属,因为它可以用作催化剂和合金添加剂。由于稀土的稀缺性和分布不均,通过回收来稳定稀土的价格和供应是非常重要的。因此,有必要开发从废催化剂和合金的酸浸液中回收稀土的方法。本研究提出了一种从含Re的盐酸(HCl)中利用伯胺回收Re的新方法。用4-己基苯胺(HexAni)从盐酸溶液中成功地回收了Re。分别以2-乙基己胺和HexAni为沉淀剂实现了铂(Pt)和稀土的分离。我们还成功地使用HexAni从含有Re、铝、钒、钴和镍的HCl溶液中选择性和定量地沉淀了Re。用HexAni沉淀法从HCl溶液中回收Re是一种很有前途的分离和回收方法。
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第一級アミンを用いたPt,Al,V,Co,Niを含む塩酸溶液からのRe沈殿回収
Rhenium (Re) is an industrially important metal because of its use in catalysts and additives in alloys. Due to the rarity and maldistribution of Re, stabilization of its price and supply by recycling is quite important. Therefore, it is necessary to develop Re recovery methods from acid leach solutions of spent catalysts and alloys. In this study, we present a new Re recovery method using primary amines from Re-containing hydrochloric acid (HCl). Re was successfully recovered from HCl solutions as precipitates using 4-hexylaniline (HexAni). Separation of platinum (Pt) and Re was achieved using 2-ethylhexylamine and HexAni as precipitants, respectively. We also succeeded in the selective and quantitative precipitation of Re using HexAni from the HCl solution containing Re, aluminum, vanadium, cobalt, and nickel. Precipitation recovery method of Re using HexAni from HCl solutions is a promising candidate for Re separation and recycling.
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