Kazuya MATSUMOTO, Rio FUJII, Yuki HATA, Mitsutoshi JIKEI
{"title":"从含有Pt、Al、V、Co、Ni的一级胺的盐酸溶液中进行Re沉淀回收","authors":"Kazuya MATSUMOTO, Rio FUJII, Yuki HATA, Mitsutoshi JIKEI","doi":"10.4144/rpsj.70.5","DOIUrl":null,"url":null,"abstract":"Rhenium (Re) is an industrially important metal because of its use in catalysts and additives in alloys. Due to the rarity and maldistribution of Re, stabilization of its price and supply by recycling is quite important. Therefore, it is necessary to develop Re recovery methods from acid leach solutions of spent catalysts and alloys. In this study, we present a new Re recovery method using primary amines from Re-containing hydrochloric acid (HCl). Re was successfully recovered from HCl solutions as precipitates using 4-hexylaniline (HexAni). Separation of platinum (Pt) and Re was achieved using 2-ethylhexylamine and HexAni as precipitants, respectively. We also succeeded in the selective and quantitative precipitation of Re using HexAni from the HCl solution containing Re, aluminum, vanadium, cobalt, and nickel. Precipitation recovery method of Re using HexAni from HCl solutions is a promising candidate for Re separation and recycling.","PeriodicalId":20971,"journal":{"name":"Resources Processing","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"第一級アミンを用いたPt,Al,V,Co,Niを含む塩酸溶液からのRe沈殿回収\",\"authors\":\"Kazuya MATSUMOTO, Rio FUJII, Yuki HATA, Mitsutoshi JIKEI\",\"doi\":\"10.4144/rpsj.70.5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Rhenium (Re) is an industrially important metal because of its use in catalysts and additives in alloys. Due to the rarity and maldistribution of Re, stabilization of its price and supply by recycling is quite important. Therefore, it is necessary to develop Re recovery methods from acid leach solutions of spent catalysts and alloys. In this study, we present a new Re recovery method using primary amines from Re-containing hydrochloric acid (HCl). Re was successfully recovered from HCl solutions as precipitates using 4-hexylaniline (HexAni). Separation of platinum (Pt) and Re was achieved using 2-ethylhexylamine and HexAni as precipitants, respectively. We also succeeded in the selective and quantitative precipitation of Re using HexAni from the HCl solution containing Re, aluminum, vanadium, cobalt, and nickel. Precipitation recovery method of Re using HexAni from HCl solutions is a promising candidate for Re separation and recycling.\",\"PeriodicalId\":20971,\"journal\":{\"name\":\"Resources Processing\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Resources Processing\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4144/rpsj.70.5\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Resources Processing","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4144/rpsj.70.5","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Rhenium (Re) is an industrially important metal because of its use in catalysts and additives in alloys. Due to the rarity and maldistribution of Re, stabilization of its price and supply by recycling is quite important. Therefore, it is necessary to develop Re recovery methods from acid leach solutions of spent catalysts and alloys. In this study, we present a new Re recovery method using primary amines from Re-containing hydrochloric acid (HCl). Re was successfully recovered from HCl solutions as precipitates using 4-hexylaniline (HexAni). Separation of platinum (Pt) and Re was achieved using 2-ethylhexylamine and HexAni as precipitants, respectively. We also succeeded in the selective and quantitative precipitation of Re using HexAni from the HCl solution containing Re, aluminum, vanadium, cobalt, and nickel. Precipitation recovery method of Re using HexAni from HCl solutions is a promising candidate for Re separation and recycling.