电解金属织物电极的减蚀增氢研究

Alara Yilmaz
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摘要

随着我们进入绿色能源可持续发展的时代,氢气现在被公认为最具未来感的能源载体之一。获得氢的一种相对经济和有效的方法是通过水电解,重点是它的纯度,从而选择电极,电解质和操作条件。然而,在水电解过程中,电极腐蚀和金属沉积等是该装置长期运行需要克服的关键限制。本研究探讨了织物金属电极的可行性,以减少电极侵蚀,并产生一致的氢气输出,使用改进的Brownlee电解装置,织物类型和包裹长度的变量。这些变量用三种品牌的金属织物进行了检验:TitanRF、Ripstop Silver和Blocwifi屏蔽织物。我们的实验结果表明,在盐浓度生成率为1.2%的情况下,Blocwifi屏蔽织物的产氢效率最高,是无金属织物基线研究的6倍(P>0.05)。此外,对电极侵蚀的目视评价表明,金属织物电极的侵蚀程度远小于铂电极。因此,研究得出结论,金属织物电极增加了氢气的产生。进一步的研究可能对详细阐明其潜在的机制和确定金属织物电极的最佳制造是有价值的。
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Investigating the Metallic Fabric Electrodes of Water Electrolysis for Corrosion Reduction and Hydrogen Generation Enhancement
As we enter an era of green energy sustainability, hydrogen gas is now recognized as one of the most futuristic energy carriers. A relatively economic and efficient way to obtain hydrogen is through water electrolysis, focusing on its degree of purity and consequently on the choice of the electrode, electrolyte, and operating conditions. However, in water electrolysis, electrode erosion, and metallic deposition, among others, are crucial limitations to overcome for the unit's long-term operation. This study explored the feasibility of fabric metallic electrodes to minimize electrode erosion and generate a consistent hydrogen output using the modified Brownlee electrolysis apparatus with the variables of types of fabrics and their wrapped lengths. These variables were examined with three brands of metallic fabric: TitanRF, Ripstop Silver, and Blocwifi Shielding fabric. Our experiments resulted in Blocwifi shielding fabric being the most efficient at consistent hydrogen generation with a 1.2% salt concentration generation rate, which was six times that of the baseline study without metallic fabric (P>0.05). Additionally, the visual evaluation of the electrode erosion showed that the metallic fabric electrodes were far less erosive than the platinum electrodes. Therefore, the study concluded that metallic fabric electrodes increase hydrogen generation. More studies might be worthwhile for detailed elucidation of the underlying mechanism and for defining the optimal fabrication of metallic fabric electrodes.
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