盐焙烧因素对钒精矿水浸的影响试验设计

Min-seuk Kim, Kyeong-woo Chung, Rina Kim
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摘要

通过试验设计(DOE)研究了盐焙烧条件对钒精矿水浸的影响。实验采用随机序列,采用2水平、3次重复、中心点设计。焙烧温度为1000℃、1200℃,硫酸钠在钠盐中的比例为30%、70%。经t检验和方差分析,各因子水平的变化对钒浸出率的影响均无统计学意义,显著性水平为0.05,30 min内钒浸出率在80 ~ 90%之间。各因素及交互作用对铝浸出率的影响均有统计学意义。温度和硫酸钠配比越高,铝浸出率越高,而各因素的交互作用则相反。焙烧钒精矿在1000℃/硫酸钠比为30%和1200℃/硫酸钠比为70%条件下的水浸,铝浸出率分别为8.96%和0%。通过回归分析得出铝浸出模型方程,r²为0.9960。
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Effect of Salt Roasting Factors on Water Leaching of Vanadium Concentrate by Design of Experiment
We investigated the effect of salt roasting conditions on vanadium concentrate's water leaching by Design of Experiment (DOE). The experiments were done by a random sequence using the design of 2-level and three repetitions with a central point. The factors and their levels were roasting temperature 1000, 1200 °C, sodium sulfate ratio in sodium salt 30, 70 %. The change in factor level did not give a statistically meaningful effect on the vanadium leaching ratio based on T-test and ANOVA with a significance level of 0.05, and the vanadium leaching ratio was between 80 and 90 % in 30 minutes. In contrast, the factors and interaction had a statistically significant effect on the aluminum leaching ratio. Higher temperature and sodium sulfate ratio produce a higher aluminum leaching ratio, whereas the interaction of factors showed the opposite. Water leaching of roasted vanadium concentrate at 1000 °C/sodium sulfate ratio of 30 % and 1200 °C/70 % resulted in 8.96 % and 0 % of aluminum leaching ratio, respectively. A regression analysis produced an aluminum leaching model equation with an R-squared of 0.9960.
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