导电涂层对银/氯化银阴极保护的影响

Karyanto Herlambang, None Pradipta Dwi Briyantama
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摘要

阴极保护系统中管土电位的测量是监测所安装阴极保护系统性能的一项必要工作。在测量管道对土壤电位时,主要的测量工具是参比电极。参比电极的稳定性对测量结果的验证非常重要。到目前为止,由于环境的频繁变化,参比电极的稳定性很难维持,特别是对于埋在地下或安装在海水中的永久性参比电极。海水中常用的永久性参比电极传感器是Ag/AgCl参比电极,但实际上Ag/AgCl参比电极一般不稳定,必须用KCl溶液稳定等问题印尼尚未生产。本研究将通过在Ag/AgCl电极上添加导电层来进行,从而提高其稳定性。传感器的制造过程从预处理、电解和产品表征开始。结果表明,在电压变化和时间变化(4000mV和60分钟)下,涂层厚度和增重效果最佳。导电固体材料的存在使Ag/AgCl层的耐蚀性从0.00391 mm/年提高到0.19549 mm/年,并使Ag/AgCl层的稳定性提高±5 mV。
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Effect of Conductive Coating on Silver/Silver Chloride Electrodes for Cathodic Protection Application
Measurement of pipe to soil potential in a cathodic protection system is something that must be done which aims to monitor the performance of the installed cathodic protection system. The main measuring tool in measuring pipe to soil potential is the reference electrode. The stability of the reference electrode is important as a validation of the measurement results. So far, the stability of the reference electrode is very difficult to maintain due to frequent changes caused by the environment, especially for permanent reference electrodes that are buried in the underground or installed in seawater. Permanent reference electrode sensors commonly used in seawater is the Ag/AgCl reference electrode, but in fact the Ag/AgCl reference electrode is generally unstable and must be stabilized with a KCl solution and other problems have not been produced in Indonesia. This research will be carried out by adding a conductive layer to the Ag/AgCl electrode so that its stability can be increased. The sensor manufacturing process starts from pretreatment, electrolysis and product characterization. The results of the best coating thickness and weight gain experiments showed by the highest voltage variations and time variations (4000mV and 60 minutes). The presence of conductive solid material increases corrosion resistance from 0.00391 mm/year to 0.19549 mm/year and increases the stability of the Ag/AgCl layer ± 5 mV.
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