高环境条件下可变涡流对非预混燃料柔性燃烧器排放的影响

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-10-17 DOI:10.1115/1.4063786
Daniel Pugh, Philip Bowen, Rukshan Navaratne, Burak Goktepe, Anthony Giles, Agustin Valera Medina, Steven Morris, Robin Vivoli
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引用次数: 0

摘要

随着替代燃料被指定为未来的能源应用,灵活的燃烧室设计需要大量的开发,以确保稳定运行,减少氮氧化物排放。使用非预混可变涡流燃烧器,实验评估了CH4 NH3和H2火焰以及中间燃料混合物在NO生成途径中的变化。为了保持燃料之间的热功率和火焰温度相等,将预热过的反应物(500 K)提供给燃烧器,并对压力(1 - 6 bara)和涡流数(0.8 - 2.0)进行参数改变。NO的产生与火焰结构和拓扑结构的变化一起被表征,并与废气排放证明了相关性。NO的产生对燃烧室压力很敏感,这为CH4和H2火焰提供了预期的增加。随着旋流数的变化,NH3和H2火焰的发射曲线明显增强。随着H2混合物中NH3组分的增加,NO排放量随压力的增加和混合物比例的变化呈衰减趋势。然而,随着旋流数的变化,这种行为明显增强,这表明在压力增加的情况下,进一步降低是可能的。在低旋流/高压条件下,NH3/H2混合物的性能优于纯H2,提供更低的NO浓度。使用传统的干/氧校正对排放数据进行归一化,同时使用热电进行质量缩放,并提供比较。研究了相应的发射形成途径的差异,以及高速OH*化学发光,以进一步阐明研究结果。
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Influence of Variable Swirl On Emissions in a Non-Premixed Fuel-Flexible Burner At Elevated Ambient Conditions
Abstract As alternative fuels are designated for future energy applications, flexible combustor designs require considerable development to ensure stable operation with reduced NOx emissions. A non-premixed variable swirl burner was used to experimentally appraise changes in NO production pathways, with CH4 NH3, and H2 flames, alongside intermediate fuel blends. Maintaining an equivalent thermal power and flame temperature between fuels, preheated reactants (500 K) were supplied to the burner, with parametric changes made to pressure (1 - 6 bara) and swirl number (0.8 - 2.0). NO production was characterized, alongside variations in flame structure and topology, with a correlation demonstrated for exhaust emissions. NO production was shown to be sensitive to combustor pressure, providing an expected increase for CH4 and H2 flames. Emission profiles from both NH3 and H2 flames are shown to be significantly augmented by a change in swirl number. As NH3 fractions were increased in the H2 blend, a decaying trend in NO emissions was observed with an increase in pressure, and as a function of mixture ratio. However, this behaviour was markedly augmented by a change in swirl number and suggests that further reductions may be possible at increased pressure. At the low swirl/high pressure condition the NH3/H2 blend outperformed pure H2, providing lower NO concentrations. Emissions data were normalised using the traditional dry/O2 correction, alongside mass scaled by thermal power, with a comparison provided. The corresponding differences in emission formation pathways were investigated, alongside high-speed OH* chemiluminescence to further elucidate findings.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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