Daniel Pugh, Philip Bowen, Rukshan Navaratne, Burak Goktepe, Anthony Giles, Agustin Valera Medina, Steven Morris, Robin Vivoli
{"title":"高环境条件下可变涡流对非预混燃料柔性燃烧器排放的影响","authors":"Daniel Pugh, Philip Bowen, Rukshan Navaratne, Burak Goktepe, Anthony Giles, Agustin Valera Medina, Steven Morris, Robin Vivoli","doi":"10.1115/1.4063786","DOIUrl":null,"url":null,"abstract":"Abstract As alternative fuels are designated for future energy applications, flexible combustor designs require considerable development to ensure stable operation with reduced NOx emissions. A non-premixed variable swirl burner was used to experimentally appraise changes in NO production pathways, with CH4 NH3, and H2 flames, alongside intermediate fuel blends. Maintaining an equivalent thermal power and flame temperature between fuels, preheated reactants (500 K) were supplied to the burner, with parametric changes made to pressure (1 - 6 bara) and swirl number (0.8 - 2.0). NO production was characterized, alongside variations in flame structure and topology, with a correlation demonstrated for exhaust emissions. NO production was shown to be sensitive to combustor pressure, providing an expected increase for CH4 and H2 flames. Emission profiles from both NH3 and H2 flames are shown to be significantly augmented by a change in swirl number. As NH3 fractions were increased in the H2 blend, a decaying trend in NO emissions was observed with an increase in pressure, and as a function of mixture ratio. However, this behaviour was markedly augmented by a change in swirl number and suggests that further reductions may be possible at increased pressure. At the low swirl/high pressure condition the NH3/H2 blend outperformed pure H2, providing lower NO concentrations. Emissions data were normalised using the traditional dry/O2 correction, alongside mass scaled by thermal power, with a comparison provided. The corresponding differences in emission formation pathways were investigated, alongside high-speed OH* chemiluminescence to further elucidate findings.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Variable Swirl On Emissions in a Non-Premixed Fuel-Flexible Burner At Elevated Ambient Conditions\",\"authors\":\"Daniel Pugh, Philip Bowen, Rukshan Navaratne, Burak Goktepe, Anthony Giles, Agustin Valera Medina, Steven Morris, Robin Vivoli\",\"doi\":\"10.1115/1.4063786\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract As alternative fuels are designated for future energy applications, flexible combustor designs require considerable development to ensure stable operation with reduced NOx emissions. A non-premixed variable swirl burner was used to experimentally appraise changes in NO production pathways, with CH4 NH3, and H2 flames, alongside intermediate fuel blends. Maintaining an equivalent thermal power and flame temperature between fuels, preheated reactants (500 K) were supplied to the burner, with parametric changes made to pressure (1 - 6 bara) and swirl number (0.8 - 2.0). NO production was characterized, alongside variations in flame structure and topology, with a correlation demonstrated for exhaust emissions. NO production was shown to be sensitive to combustor pressure, providing an expected increase for CH4 and H2 flames. Emission profiles from both NH3 and H2 flames are shown to be significantly augmented by a change in swirl number. As NH3 fractions were increased in the H2 blend, a decaying trend in NO emissions was observed with an increase in pressure, and as a function of mixture ratio. However, this behaviour was markedly augmented by a change in swirl number and suggests that further reductions may be possible at increased pressure. At the low swirl/high pressure condition the NH3/H2 blend outperformed pure H2, providing lower NO concentrations. Emissions data were normalised using the traditional dry/O2 correction, alongside mass scaled by thermal power, with a comparison provided. 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Influence of Variable Swirl On Emissions in a Non-Premixed Fuel-Flexible Burner At Elevated Ambient Conditions
Abstract As alternative fuels are designated for future energy applications, flexible combustor designs require considerable development to ensure stable operation with reduced NOx emissions. A non-premixed variable swirl burner was used to experimentally appraise changes in NO production pathways, with CH4 NH3, and H2 flames, alongside intermediate fuel blends. Maintaining an equivalent thermal power and flame temperature between fuels, preheated reactants (500 K) were supplied to the burner, with parametric changes made to pressure (1 - 6 bara) and swirl number (0.8 - 2.0). NO production was characterized, alongside variations in flame structure and topology, with a correlation demonstrated for exhaust emissions. NO production was shown to be sensitive to combustor pressure, providing an expected increase for CH4 and H2 flames. Emission profiles from both NH3 and H2 flames are shown to be significantly augmented by a change in swirl number. As NH3 fractions were increased in the H2 blend, a decaying trend in NO emissions was observed with an increase in pressure, and as a function of mixture ratio. However, this behaviour was markedly augmented by a change in swirl number and suggests that further reductions may be possible at increased pressure. At the low swirl/high pressure condition the NH3/H2 blend outperformed pure H2, providing lower NO concentrations. Emissions data were normalised using the traditional dry/O2 correction, alongside mass scaled by thermal power, with a comparison provided. The corresponding differences in emission formation pathways were investigated, alongside high-speed OH* chemiluminescence to further elucidate findings.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.