天然橡胶-丙烯酸多元醇树脂低碳钢防护涂层体系的研制

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED Pigment & Resin Technology Pub Date : 2023-10-16 DOI:10.1108/prt-06-2023-0055
Monapriya Naidu Kerinasamy Naidu, Iling Aema Wonnie Ma, Sachin Sharma Ashok Kumar, Vengadaesvaran Balakrishnan, Ramesh Subramaniam, Ramesh Kasi
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引用次数: 0

摘要

目的研究环氧化天然橡胶与丙烯酸多元醇树脂在低碳钢板上的防护涂层体系。设计/方法/方法在这项工作中,采用环氧化天然橡胶基材料和有机树脂(丙烯酸树脂)开发粘合剂涂料,用于金属基材的防腐。通过改变环氧化天然橡胶(ENR)和丙烯酸树脂的组成,开发了七种不同的多功能涂料样品。利用傅里叶变换红外光谱(FTIR)和电化学阻抗谱(EIS)等分析方法对涂层的性能进行了表征。在3.5 wt.%的氯化钠中浸泡30天后,进行了EIS测试,以评估其耐腐蚀性。采用十字切口试验机(CHT)对胶粘剂的粘接性能进行了研究。紫外可见光谱(UV-Vis)也被用于评估天然橡胶基涂层系统的涂膜透明度的变化。发现制备的涂层在基体上形成了均匀的涂层。结果表明,涂层具有良好的附着力。ENR浓度越高,透明度越高,透明度随丙烯酸浓度的增加而降低。FTIR分析证实了涂层组分之间发生的交联。根据EIS的阻抗数据,天然橡胶的掺入可以作为防腐添加剂,即使在浸泡30天后,其涂层电阻值也远高于108Ω。该方法为提高丙烯酸多元醇树脂与环氧化天然橡胶的强度和粘接性能提供了一种简单实用的解决方案。长期应用仍需改进。这项工作是在我们实验室进行的。天然橡胶基材料与有机树脂相结合是涂料研究的新途径。
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Development of protective coating system using natural rubber – acrylic polyol resin for mild steel
Purpose The purpose of this study is to develop a protective coating system on mild steel panel incorporating epoxidized natural rubber with acrylic polyol resin. Design/methodology/approach In this work, a novel attempt is made to develop binder coatings using epoxidized natural rubber-based material and an organic resin (acrylic resin) for corrosion protection on metal substrate. Seven different samples of multifunctional coatings are developed by varying the compositions of epoxidized natural rubber (ENR) and acrylic resin. The properties of the developed coatings have been characterized using analytical methods such as Fourier transform infrared spectroscopy (FTIR) and electrochemical impedance spectroscopy (EIS). EIS has been carried out for 30 days to evaluate the corrosion resistance after immersing into 3.5 wt.% of sodium chloride. Cross hatch cut tester (CHT) has been used to study the adhesive properties. UV–Visible Spectroscopy (UV–Vis) was also used to assess changes in the coating-film transparency of the natural rubber-based coating systems in this study. Findings The developed coatings have formed uniform layer on the substrate. CHT results show excellent adhesion of the coatings. Higher concentrations of ENR have higher transparency level, which reduces when the acrylic concentration increases. FTIR analysis confirms the crosslinking that occurred between the components of the coatings. Based on the impedance data from EIS, the incorporation of natural rubber can be an additive for the corrosion protection, which has the coating resistance values well above 108Ω even after 30 days of immersion. Practical implications The blending method provides a simple and practical solution to improve the strength and adhesion properties of acrylic polyol resin with epoxidized natural rubber. There is still improvement needed for long-term applications. Originality/value The work has been conducted in our laboratory. The combination of natural rubber-based materials and organic resins is a new approach in coating research.
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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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