硬球气体的统计动力学:波动玻尔兹曼方程和大偏差

IF 8.3 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Applied Materials & Interfaces Pub Date : 2023-11-01 DOI:10.4007/annals.2023.198.3.3
Thierry Bodineau, Isabelle Gallagher, Laure Saint-Raymond, Sergio Simonella
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引用次数: 25

摘要

我们提出了在玻尔兹曼-格拉德极限下硬球气体的动态涨落的数学理论。我们证明了(1)由Boltzmann方程的解得到的经验测度的涨落,以平均粒子数的平方根为尺度,收敛于由波动的Boltzmann方程驱动的高斯过程,正如Spohn所预测的那样;(2)大偏差在平均粒子数中呈指数小,在规则假设下,由Rezakhanlou先前在随机碰撞动力学中得到的大偏差泛函来表征。结果在远离热平衡的情况下是有效的,但只在短时间内有效。我们的策略是基于累积生成函数的统一先验界,表征小相关性的精细结构。
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Statistical dynamics of a hard sphere gas: fluctuating Boltzmann equation and large deviations
We present a mathematical theory of dynamical fluctuations for the hard sphere gas in the Boltzmann-Grad limit. We prove that (1) fluctuations of the empirical measure from the solution of the Boltzmann equation, scaled with the square root of the average number of particles, converge to a Gaussian process driven by the fluctuating Boltzmann equation, as predicted by Spohn; (2) large deviations are exponentially small in the average number of particles and are characterized, under regularity assumptions, by a large deviation functional as previously obtained by Rezakhanlou for dynamics with stochastic collisions. The results are valid away from thermal equilibrium, but only for short times. Our strategy is based on uniform a priori bounds on the cumulant generating function, characterizing the fine structure of the small correlations.
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来源期刊
ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces 工程技术-材料科学:综合
CiteScore
16.00
自引率
6.30%
发文量
4978
审稿时长
1.8 months
期刊介绍: ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.
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