木质纤维素生物质生产糠醛和乙酰丙酸的模拟

Jabosar Ronggur Hamonangan Panjaitan
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引用次数: 0

摘要

糠醛和乙酰丙酸是可以从木质纤维素生物质中产生的化学物质。本研究对100吨生物质/年生产糠醛和乙酰丙酸的质量平衡模拟进行了研究。本研究采用多种动力学反应模型和生物质与溶剂的比例,从木质纤维素生物质原料中提取由纤维素、半纤维素、木质素、灰分和水组成的35%、30%、25%、3%和7%。本研究采用的动力学模型为分离动力学模型和同时动力学模型(模型3)。将分离动力学模型分为分离动力学模型1(模型1)和分离动力学模型2(模型2)两个模型。采用SuperPro Designer 9.0软件进行质量平衡模拟计算。研究发现,反应动力学模型的变化影响了糠醛和乙酰丙酸的生成。较高的生物质与溶剂比产生较高的糠醛和乙酰丙酸产量。在生物质与溶剂比为1:30、糠醛含量为0.67 l/h的动力学反应模式-2下,模拟过程中糠醛产量最高。而模拟过程中乙酰丙酸产量最高的是动力学反应模型-1,生物质与溶剂比为1:30,乙酰丙酸/小时为2.37升。
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Simulation of Furfural and Levulinic Acid Production from Lignocellulosic Biomass
Furfural and levulinic acid are chemicals that can be produced from lignocellulosic biomass. In this research, mass balance simulation of furfural and levulinic acid production at scale of 100 tons of biomass/year was examined. This research using various models of kinetic reaction and biomass to solvent ratio from lignocellulosic biomass raw materials consisting of cellulose, hemicellulose, lignin, ash, and water composition of 35%, 30%, 25%, 3%, and 7%. The kinetic models used in this research were separate kinetic models and simultaneous model (model-3). The separate kinetic models were divided into two models which separate kinetic model 1 (model-1) and separate kinetic model 2 (model-2). SuperPro Designer 9.0 software was used to calculate mass balance simulation. From the research, it was found that variations in kinetic reaction model affected furfural and levulinic acid production. Higher biomass to solvent ratio produced higher furfural and levulinic acid production. The highest furfural produced from simulation process was kinetic reaction model-2 with a biomass to solvent ratio of 1:30 and 0.67 liter furfural/hour. While the highest levulinic acid produced from the simulation process was kinetic reaction model-1 with a biomass to solvent ratio of 1:30 and 2.37 liter levulinic acid/hour.
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审稿时长
12 weeks
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