MgO和水合石灰对甲基叔丁基醚污染粘土的稳定固化研究

A. R. Estabragh, A. Ansar Shourijeh, K. Rezaei, A. A. Javadi, M. Amini
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摘要

近年来,氧化镁(MgO)作为一种修复污染土壤的新药剂受到了研究人员的重视。研究了氧化镁和水合石灰对MTBE(甲基丁基醚)污染粘土的修复效果。采用每公斤土壤添加2.25 g甲基叔丁基醚的方法人工制备污染土壤。在自然土壤和污染土壤中分别添加不同比例的MgO(0.125、0.25、0.5、5、10、20%)和石灰(2.5、5、10%)。结果表明,通过增加MgO或石灰的掺量和养护时间,可以提高天然土和污染土的强度。浸出试验结果表明,添加5%、10%和20% MgO时,土壤样品中存在的MTBE全部被去除,而当MgO添加比例较低(0.125、0.25和0.5%)时,MTBE浓度随时间降低。浸出试验结果还表明,水合石灰能有效降低MTBE的浓度。MTBE浓度的降低量取决于氧化镁或水合石灰的百分比。两种粘结剂对MTBE的去除效果比较表明,MgO对MTBE的去除效果优于水合石灰。
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Stabilization and Solidification of a Clay Soil Contaminated with MTBE by Using MgO and Hydrated Lime
In recent years, magnesium oxide (MgO) has been considered by researchers as a new agent for the remediation of contaminated soils. In this paper, the effect of MgO and hydrated lime on the remediation of a clay soil contaminated with MTBE (Methyl Butyl Ether) was studied. The contaminated soil was made artificially by adding 2.25 g MTBE per kg of soil. MgO with different percentages (0.125, 0.25, 0.5, 5, 10, and 20%) and lime with 2.5, 5, and 10% percentages were added to the natural and contaminated soil. The results showed that by increasing the percentage of MgO or lime and curing time, the strength of natural and contaminated soil was improved. The results of the leaching tests showed that by adding 5, 10, or 20% MgO, all the existing MTBE in the soil samples were removed while for the smaller percentages of MgO (0.125, 0.25, and 0.5%) there was a decrease in the concentration of MTBE with time. The results of the leaching tests also revealed that the hydrated lime was effective in reducing the concentration of MTBE. The amount of reduction in the concentration of MTBE was dependent on the percentage of MgO or hydrated lime. The comparison of the results of the two binders showed that MgO was more effective than the hydrated lime in removing the MTBE from the soil.
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