2,2′-三硫化二基二苯甲酰氯

IF 0.6 Q4 CHEMISTRY, ORGANIC Molbank Pub Date : 2023-09-21 DOI:10.3390/m1731

R. Alan Aitken, Alexandra H. Campbell, Chloé E. Fletcher, Alexandra M. Z. Slawin

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引用次数: 0

摘要

标题化合物的x射线结构是由硫代水杨酸与亚硫酰氯在低转化率下形成的。酸性氯基取向，以允许有吸引力的非键O…S相互作用。提出了这种意外产物形成的机理。主要反应产物2-巯基苯甲酰氯的1H和13C NMR数据也首次被报道。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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2,2′-Trisulfanediyldibenzoyl Chloride

The X-ray structure of the title compound, formed at low conversion in the reaction of thiosalicylic acid with thionyl chloride, has been determined. The acid chloride groups are oriented to permit an attractive non-bonding O…S interaction. Mechanisms are suggested for the formation of this unexpected product. 1H and 13C NMR data are also reported for the first time for the major reaction product, 2-mercaptobenzoyl chloride.

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)