获得有机官能团 Silsesquioxane 的现代方法

IF 1.6 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series C Pub Date : 2023-10-10 DOI:10.1134/S181123822370039X
N. S. Bredov, V. V. Kireev, V. A. Polyakov, I. B. Sokol’skaya, A. S. Esin
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引用次数: 0

摘要

本研究探讨了有机功能低聚硅倍半氧烷合成领域的现代研究。研究显示了低聚有机硅倍半氧烷的组成和结构与硅原子结合的有机基中含有各种官能团(如甲基丙烯酸基、氨基丙基、羧基和环三磷酸基)的有机三烷氧基硅烷在水解和酸水解缩聚过程中的形成条件之间的关系。对有机官能团不完全缩合低聚硅倍半氧烷的合成方法进行了比较分析。
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Modern Approaches to Obtaining Organofunctional Silsesquioxanes

Modern research in the field of synthesis of organofunctional oligosilsesquioxanes is considered. Relationships between the composition and structure of oligomeric organosilsesquioxanes and the conditions for their formation during the hydrolytic and acidohydrolytic polycondensation of organotrialkoxysilanes containing various functionalities, such as methacrylic, aminopropyl, carboxyl, and cyclotriphosphazene groups, in organic radicals bonded to silicon atoms are shown. A comparative analysis of approaches to the synthesis of organofunctional incompletely condensed oligosilsesquioxanes has been carried out.

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来源期刊
Polymer Science, Series C
Polymer Science, Series C 工程技术-高分子科学
CiteScore
3.00
自引率
4.50%
发文量
21
审稿时长
>12 weeks
期刊介绍: Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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