聚苯胺/二氧化钛纳米复合材料的光学和结构表征

IF 0.5 Q4 PHYSICS, MULTIDISCIPLINARY Jordan Journal of Physics Pub Date : 2023-06-30 DOI:10.47011/16.2.4
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引用次数: 0

摘要

摘要/ Abstract摘要:采用原位化学聚合的方法,在冰浴介质中合成了聚苯胺/二氧化钛复合材料(PANI/TiO2)。采用紫外-可见分光光度计、傅里叶变换红外光谱仪、x射线衍射仪和扫描电镜对材料进行了表征。XRD谱图显示,不同TiO2配比的纯聚苯胺和聚苯胺/TiO2复合材料具有多晶结构。傅里叶变换红外光谱研究了聚苯胺的存在。紫外可见光谱分析表明,PANI/TiO2的能隙随着TiO2纳米粒子比例的增加而减小。关键词:导电聚合物,聚苯胺(PANI),二氧化钛(TiO2),结构表征,光学性能,PANI复合材料
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Optical and Structural Characterization of Polyaniline/Titanium Dioxide Nano Composites
Abstract: Polyaniline/ titanium dioxide composite (PANI/TiO2) was synthesized by in-situ chemical polymerization in an ice bath medium for polyaniline with different percentages of TiO2 nanoparticles (3, 6, and 9) wt. %. UV-Vis spectrophotometer, Fourier Transforms Infrared (FTIR) spectrometer, X-ray diffraction (XRD), and Scanning Electron Microscopy (SEM) were used to characterize the materials. The XRD patterns showed polycrystalline structure for PURE PANI and PANI/TiO2 composite of different TiO2 ratios. The FT-IR investigated the presence of polyaniline. The analysis of UV-Vis spectra revealed that the energy gap for PANI/TiO2 decreased with increasing the ratios of TiO2 nanoparticles. Keywords: Conducting polymer, Polyaniline (PANI), Titanium dioxide (TiO2), Structure characterization, Optical properties, PANI composite.
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来源期刊
Jordan Journal of Physics
Jordan Journal of Physics PHYSICS, MULTIDISCIPLINARY-
CiteScore
0.90
自引率
14.30%
发文量
38
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