磺苯酞指示染料的可逆光异构化II

U.-W. Grummt
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引用次数: 0

摘要

介绍了溴甲酚绿和百里酚蓝的闪光光解实验结果。他们进一步支持了最近提出的复杂机制:光诱导的旋转异构化之后是两个连续的质子转移反应,偶尔会有一个中间的硫酮环闭合。
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Reversible photoisomerizations of sulfonephthalein indicator dyes II

Experimental results of a flash photolysis study of bromo cresol green and thymol blue are presented. They give further support to the recently proposed complex mechanism: A photoinduced rotational isomerization is followed by two consecutive proton transfer reactions and, occasionally, by an intermediate sultone ring closure.

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