Sebastian Jun Kai Guek , Li Ji , James Wen Liang Loke , Hwee Ling Koh , Wai Yip Fan
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Nickel(II) phosphine-catalysed hydrodehalogenation of aryl halides under mild ambient conditions
A convenient and low-cost hydrodehalogenation process catalysed by air-stable nickel(II) complexes containing bidentate phosphine ligands has been developed under ambient conditions with sodium borohydride acting as the reducing agent and hydrogen atom source. High conversions of aryl halides, including polyfluorinated substrates, into their hydrogenated counterparts have been achieved in dimethylformamide (DMF) and to a moderate extent, in DMF/isopropanol (10:90% v/v) solvent mixture. A mechanism has been proposed to account for the experimental data.
期刊介绍:
Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are:
Heterogeneous catalysis including immobilized molecular catalysts
Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis
Photo- and electrochemistry
Theoretical aspects of catalysis analyzed by computational methods