[凝胶法结晶磷灰石形成的研究]。

T Endo, N Amano, M Yoshida, H Murakami, N Kosuge, Y Ohmi, A Kameda
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引用次数: 0

摘要

研究了用硅水凝胶法用硝酸钙(I族)或氯化钙(II族)制备的磷灰石和明胶凝胶法用硝酸钙(III族)或氯化钙(IV族)制备的磷灰石的形成体积以及形成条件,测定了pH值,计算了Ca/P比,估计了氯离子,用扫描电镜进行了形态观察。通过x射线衍射定性分析(鉴定、晶粒大小、晶格缺陷、晶格常数)和红外吸收光谱成分分析,用凝胶法对磷灰石的形成进行了分析。结果表明,I-II组与III-IV组之间无明显差异,提示氯化钙和硝酸钙凝胶法制备满意的氟磷灰石是可能的。
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[A study on the formation of apatite crystallized with gel method].

About apatite produced with a silicahydro gel method using calcium nitrate (group I) or calcium chloride (group II) and a gelatin gel method by use of calcium nitrate (group III) or calcium chloride (group IV), the formative volume as well as the formative condition of a periodic-layered precipitate (Liesegang ring), the pH measurement, calculation of Ca/P ratio, an estimation of the chlorine ion, morphological observation with a scanning electron microscope, qualitative analyses by X-ray diffraction (identification, crystallite size, lattice imperfections, lattice constants) and the composition analysis by infrared absorption spectroscopy were carried out to elucidate the formation of apatite using the gel method. The result showed that there were no distinct differences between group I-II and group III-IV, and it is suggested that it is possible to form satisfact fluorapatite with a gel method using calcium chloride as well as calcium nitrate.

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