{"title":"氰化物离子水溶液的放射性溶解","authors":"Qi Shengchu, Wu Jilan","doi":"10.1016/0146-5724(85)90223-7","DOIUrl":null,"url":null,"abstract":"<div><p>The yields of the radiolytic products in air, N<sub>2</sub> and N<sub>2</sub>O saturated aqueous solution of cyanide ion have been determined by combining the paper chromatographic method and carrier technique. The variations of the yields of the products in various systems have been investigated systematically by the scavenger method. The reaction kinetics of active species (OH, e<sup>-</sup><sub>aq</sub> and H) with HCN and CN<sup>-</sup> has been investigated. The <em>G</em> values of radiolytic products originating from different pathway of reactions were determined. The possibility of increasing the yields of amino acids has also been studied, and a method of increasing the <em>G</em> value of glycine has been found</p></div>","PeriodicalId":101054,"journal":{"name":"Radiation Physics and Chemistry (1977)","volume":"26 4","pages":"Pages 365-371"},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0146-5724(85)90223-7","citationCount":"0","resultStr":"{\"title\":\"Radiolysis of aqueous solution of cyanide ion\",\"authors\":\"Qi Shengchu, Wu Jilan\",\"doi\":\"10.1016/0146-5724(85)90223-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The yields of the radiolytic products in air, N<sub>2</sub> and N<sub>2</sub>O saturated aqueous solution of cyanide ion have been determined by combining the paper chromatographic method and carrier technique. The variations of the yields of the products in various systems have been investigated systematically by the scavenger method. The reaction kinetics of active species (OH, e<sup>-</sup><sub>aq</sub> and H) with HCN and CN<sup>-</sup> has been investigated. The <em>G</em> values of radiolytic products originating from different pathway of reactions were determined. The possibility of increasing the yields of amino acids has also been studied, and a method of increasing the <em>G</em> value of glycine has been found</p></div>\",\"PeriodicalId\":101054,\"journal\":{\"name\":\"Radiation Physics and Chemistry (1977)\",\"volume\":\"26 4\",\"pages\":\"Pages 365-371\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0146-5724(85)90223-7\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiation Physics and Chemistry (1977)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0146572485902237\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiation Physics and Chemistry (1977)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0146572485902237","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The yields of the radiolytic products in air, N2 and N2O saturated aqueous solution of cyanide ion have been determined by combining the paper chromatographic method and carrier technique. The variations of the yields of the products in various systems have been investigated systematically by the scavenger method. The reaction kinetics of active species (OH, e-aq and H) with HCN and CN- has been investigated. The G values of radiolytic products originating from different pathway of reactions were determined. The possibility of increasing the yields of amino acids has also been studied, and a method of increasing the G value of glycine has been found