吸附转化法处理某钛磁铁矿精矿

IF 0.4 Q4 METALLURGY & METALLURGICAL ENGINEERING Russian Metallurgy (Metally) Pub Date : 2023-12-05 DOI:10.1134/S003602952307008X
E. P. Lokshin, O. A. Tareeva
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引用次数: 0

摘要

提出并验证了湿法冶金处理某钛磁铁矿精矿的工艺。该技术包括在弱浓硫酸溶液中,在H+形式的磺酸阳离子交换树脂存在下,精矿分解,钛磁铁矿精矿的大部分金属向吸附剂过渡,形成富钛铁矿渣;用5 M氯化钠溶液解吸饱和磺酸阳离子交换树脂中的金属;分步水解沉淀分离氢氧化钛、富钒氢氧化铁、纯氢氧化铁和铁锰混合氢氧化铁;并对磺酸阳离子交换树脂进行再生。确定了各工序的最佳工艺参数。该工艺硫酸消耗弱,不产生废液。
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Processing of a Titanomagnetite Concentrate by Sorption Conversion

A hydrometallurgical technology for processing a titanomagnetite concentrate is proposed and substantiated. The technology includes the decomposition of the concentrate in a weakly concentrated sulfuric acid solution in the presence of a sulfonic cation-exchange resin in the H+ form with the transition of the major portion of metals of the titanomagnetite concentrate to the sorbent and the formation of an ilmenite-enriched residue; the desorption of metals from the saturated sulfonic cation-exchange resin with a 5 M solution of sodium chloride; the fractional hydrolytic precipitation and separation of titanium hydroxide, iron hydroxide enriched in vanadium, pure iron hydroxide, and a mixture of iron and manganese hydroxides; and the regeneration of the sulfonic cation-exchange resin. The optimum parameters of the particular processes are determined. Sulfuric acid is weakly consumed and no liquid wastes are formed in the technology.

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来源期刊
Russian Metallurgy (Metally)
Russian Metallurgy (Metally) METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
0.70
自引率
25.00%
发文量
140
期刊介绍: Russian Metallurgy (Metally)  publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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