基于低分子量聚氨基甲酸乙酯橡胶的γ辐照增塑剂的变形和强度特性

IF 0.9 4区 化学 Q4 CHEMISTRY, PHYSICAL High Energy Chemistry Pub Date : 2023-11-30 DOI:10.1134/s0018143923060127
E. Nurullaev, V. D. Oniskiv, L. L. Himenko, E. M. Ibragimova
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引用次数: 0

摘要

摘要研究了50kgy、100kgy和150kgy γ辐射剂量对PDI-3B牌低分子量聚氨酯橡胶增塑剂变形和强度性能的影响。为了评估塑化粘合剂强度随辐照剂量的变化,在223、295和323 K的温度下计算了断裂能。在这些测试温度下,与原始样品相比,随辐照剂量的增加,条件应力增加,变形略有减少。在223 K测试温度下,变形和强度特性发生了剧烈变化;辐照后试样的强度比原试样提高了4倍以上,变形比原试样略有减小。这种趋势随着测试温度的升高而持续,但差异几乎减半。伽马辐照对测试材料的这种影响可以用交联在降解过程中的普遍性来解释。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Deformation and Strength Properties of a Gamma-Irradiated Plasticized Binder Based on Low-Molecular-Weight Polydiene Urethane Rubbers

Abstract

The effect of gamma-radiation doses of 50, 100, and 150 kGy on the deformation and strength properties of a plasticized binder based on low-molecular-weight polydiene urethane rubbers of the PDI-3B brand has been studied. To assess changes in the strength of the plasticized binder depending on the dose of gamma irradiation, the fracture energies were calculated at temperatures of 223, 295, and 323 K. At these test temperatures, the conditional stress increased and deformation slightly decreased depending on the dose of gamma irradiation compared with those of the original sample. Sharp changes in the deformation and strength characteristics occurred at a test temperature of 223 K; the strength of the irradiated samples increased by a factor of more than 4, and the deformation decreased slightly compared to that of the original sample. This trend persisted with an increase in the test temperature, but the difference was almost halved. Such an effect of gamma irradiation on the test material can be explained by the prevalence of crosslinking over degradation.

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来源期刊
High Energy Chemistry
High Energy Chemistry 化学-物理化学
CiteScore
1.50
自引率
28.60%
发文量
62
审稿时长
6-12 weeks
期刊介绍: High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.
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