{"title":"利用在线近红外光谱仪研究丁二烯在 1,2-二乙氧基丙烷存在下的阴离子聚合动力学","authors":"Luis Rodriguez-Guadarrama","doi":"10.1002/mren.202300051","DOIUrl":null,"url":null,"abstract":"<p>Online near-infrared spectroscopy technique is employed to investigate the kinetics of the anionic polymerization of butadiene with n-butyllithium initiator in the presence of the microstructure modifier 1,2-diethoxypropane (DEP) in cyclohexane solvent. A phenomenological kinetic model is developed to describe the anionic polymerization process in the presence of DEP, and its influence on the microstructure of polybutadiene under different conditions is determined.</p>","PeriodicalId":18052,"journal":{"name":"Macromolecular Reaction Engineering","volume":"18 2","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigating The Kinetics of Anionic Polymerization of Butadiene in Presence of 1,2-diethoxypropane Using Online Near-Infrared Spectroscopy\",\"authors\":\"Luis Rodriguez-Guadarrama\",\"doi\":\"10.1002/mren.202300051\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Online near-infrared spectroscopy technique is employed to investigate the kinetics of the anionic polymerization of butadiene with n-butyllithium initiator in the presence of the microstructure modifier 1,2-diethoxypropane (DEP) in cyclohexane solvent. A phenomenological kinetic model is developed to describe the anionic polymerization process in the presence of DEP, and its influence on the microstructure of polybutadiene under different conditions is determined.</p>\",\"PeriodicalId\":18052,\"journal\":{\"name\":\"Macromolecular Reaction Engineering\",\"volume\":\"18 2\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-12-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Reaction Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/mren.202300051\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Reaction Engineering","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mren.202300051","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Investigating The Kinetics of Anionic Polymerization of Butadiene in Presence of 1,2-diethoxypropane Using Online Near-Infrared Spectroscopy
Online near-infrared spectroscopy technique is employed to investigate the kinetics of the anionic polymerization of butadiene with n-butyllithium initiator in the presence of the microstructure modifier 1,2-diethoxypropane (DEP) in cyclohexane solvent. A phenomenological kinetic model is developed to describe the anionic polymerization process in the presence of DEP, and its influence on the microstructure of polybutadiene under different conditions is determined.
期刊介绍：
Macromolecular Reaction Engineering is the established high-quality journal dedicated exclusively to academic and industrial research in the field of polymer reaction engineering.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
