用 BiFeO3 薄膜修饰的 TiO2 纳米管的表面功能化

Surfaces Pub Date : 2023-12-19 DOI:10.3390/surfaces7010001
Shikhgasan Ramazanov, F. Orudzhev, Gaji Gajiev
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引用次数: 0

摘要

通过原子层沉积法,可以在二氧化钛纳米管 TiO2(Nt) 凹凸不平的表面上制备出高宽比薄膜。最终获得了具有可控电气特性的改性 BiFeO3/TiO2(Nt)/Ti (BFOT)结构。BFOT 同时具有铁电和半导体特性,其非线性电导率取决于电压的大小和持续时间。对电荷变化的温度依赖性分析表明,BFOT 结构中的漏电流是由于缺陷层捕获和释放电荷载流子造成的。用多铁性 BiFeO3 对纳米管进行表面改性,可以制造出具有自适应功能特性的半导体。
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Surface Functionalization of TiO2 Nanotubes Modified with a Thin Film of BiFeO3
The atomic layer deposition method allows for the production of a thin film with a high aspect ratio on the uneven surface of titanium dioxide nanotubes TiO2(Nt). A modified BiFeO3/TiO2(Nt)/Ti (BFOT) structure with controllable electrical characteristics was obtained. BFOT possesses both ferroelectric and semiconductor properties with nonlinear conductivity dependent on the magnitude and duration of the voltage supply. Analysis of the temperature dependence of charge variation showed leakage currents in the BFOT structure due to the capture and release of charge carriers from defect levels. Surface modification of nanotubes with the multiferroic BiFeO3 allows for the creation of semiconductors with adaptive functional properties.
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