Dipayan Chakraborty, Giorgi Kharchilava, Ian Carmichael, S. Ptasińska
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引用次数: 0
摘要
利用先进的仪器探索解离电子附着研究,可以获得以前无法获得的信息。利用新构建的速度图成像光谱仪,我们重新研究了气相乙酸的离解电子附着。我们讨论了可能的碎片通道,并将相应的离子产率与之前的高电子能分辨率结果进行了比较。我们重点研究了发生在较高能量(尤其是 10 eV 附近)的通道,并计算了它们的热力学阈值。此外,我们扩展了之前的研究,在 10 eV 共振附近进行了速度切片成像,以获得碎片离子的动能分布。
Dissociative electron attachment studies of gas-phase acetic acid using a velocity map imaging technique
Advancing instrumentation to explore dissociative electron attachment studies allows previously unattainable information to be acquired. Using a newly-constructed velocity map imaging spectrometer, we revisited a study on dissociative electron attachment to gas-phase acetic acid. We discuss possible fragmentation channels and compared the corresponding ion yields with previous high-electron energy resolution results. We focus on the channels occurring at higher energies, particularly near 10 eV, and calculate their thermodynamic thresholds. Moreover, we expand previous studies and perform velocity-slice imaging near the 10 eV resonance to obtain the kinetic energy distribution of the fragment ions.
期刊介绍:
Published twice-monthly (24 issues per year), Journal of Physics B: Atomic, Molecular and Optical Physics covers the study of atoms, ions, molecules and clusters, and their structure and interactions with particles, photons or fields. The journal also publishes articles dealing with those aspects of spectroscopy, quantum optics and non-linear optics, laser physics, astrophysics, plasma physics, chemical physics, optical cooling and trapping and other investigations where the objects of study are the elementary atomic, ionic or molecular properties of processes.