{"title":"基于 Max Ti2AlC 和 (Ti,Nb)2AlC 相的涂层在 20°C 和 500°C 时的物理力学性能","authors":"","doi":"10.1007/s11003-023-00737-8","DOIUrl":null,"url":null,"abstract":"<p>Physicomechanical characteristics of 15Kh16k5N2MVFAB-Sh steel (0.15C–16Cr–5Co–2Ni–0.7V–0.6Mo–0.3Nb–0.4N): wear resistance at 20°C and 500°C and resistance to fretting fatigue at 20°C without and with coatings obtained by the method of vacuum-arc deposition using targets based on the MAX phases of <span> <span>\\({\\mathrm{Ti}}_{2}{\\mathrm{AlC}}\\)</span> </span> and <span> <span>\\({{\\mathrm{(}{\\mathrm{Ti}}}_{1-x}{\\mathrm{Nb}}_{x})}_{2}{\\mathrm{AlC}}\\)</span> </span>, where <em>x</em> = 0.1 and 0.2, are investigated. At 20°C the friction coefficient and the wear specific rate of all coatings are greater than that of the studied steel in contact with a ShKh15 steel (1.0C–1.5Cr–0.3Ni–0.3Mn–0.3Si–0.25Cu) ball under a load of 2 N. Unambiguous relationship between microhardness and tribological characteristics of materials has not been recorded. The resistance to fretting fatigue of the samples with <span> <span>\\({\\mathrm{Ti}}_{2}{\\mathrm{AlC}}\\)</span> </span> -based coating in contact with the Ni-alloy (17Cr–12W–11Fe–6Co–3Ti–1.5Nb–1.6Al) in high-cycle region (<em>N</em> > <span> <span>\\({10}^{5}\\)</span> </span> cycles) is significantly higher than that of uncoated samples. The tribological characteristics of all materials decrease at 500°C but the least for samples with <span> <span>\\({\\mathrm{Ti}}_{2}{\\mathrm{AlC}}\\)</span> </span> based coating. We have not found positive influence of niobium doping on the wear and fretting fatigue resistance of these coatings.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"11 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Physicomechanical Properties of Coatings Based on Max Ti2AlC and (Ti, Nb)2AlC Phases at 20°C and 500°C\",\"authors\":\"\",\"doi\":\"10.1007/s11003-023-00737-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Physicomechanical characteristics of 15Kh16k5N2MVFAB-Sh steel (0.15C–16Cr–5Co–2Ni–0.7V–0.6Mo–0.3Nb–0.4N): wear resistance at 20°C and 500°C and resistance to fretting fatigue at 20°C without and with coatings obtained by the method of vacuum-arc deposition using targets based on the MAX phases of <span> <span>\\\\({\\\\mathrm{Ti}}_{2}{\\\\mathrm{AlC}}\\\\)</span> </span> and <span> <span>\\\\({{\\\\mathrm{(}{\\\\mathrm{Ti}}}_{1-x}{\\\\mathrm{Nb}}_{x})}_{2}{\\\\mathrm{AlC}}\\\\)</span> </span>, where <em>x</em> = 0.1 and 0.2, are investigated. At 20°C the friction coefficient and the wear specific rate of all coatings are greater than that of the studied steel in contact with a ShKh15 steel (1.0C–1.5Cr–0.3Ni–0.3Mn–0.3Si–0.25Cu) ball under a load of 2 N. Unambiguous relationship between microhardness and tribological characteristics of materials has not been recorded. The resistance to fretting fatigue of the samples with <span> <span>\\\\({\\\\mathrm{Ti}}_{2}{\\\\mathrm{AlC}}\\\\)</span> </span> -based coating in contact with the Ni-alloy (17Cr–12W–11Fe–6Co–3Ti–1.5Nb–1.6Al) in high-cycle region (<em>N</em> > <span> <span>\\\\({10}^{5}\\\\)</span> </span> cycles) is significantly higher than that of uncoated samples. The tribological characteristics of all materials decrease at 500°C but the least for samples with <span> <span>\\\\({\\\\mathrm{Ti}}_{2}{\\\\mathrm{AlC}}\\\\)</span> </span> based coating. We have not found positive influence of niobium doping on the wear and fretting fatigue resistance of these coatings.</p>\",\"PeriodicalId\":18230,\"journal\":{\"name\":\"Materials Science\",\"volume\":\"11 1\",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-12-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11003-023-00737-8\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11003-023-00737-8","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
15Kh16k5N2MVFAB-Sh 钢(0.15C-16Cr-5Co-2Ni-0.7V-0.6Mo-0.3Nb-0.4N):在 20°C 和 500°C 时的抗磨损性,以及在 20°C 时的抗烧蚀疲劳性(无涂层和有涂层)。({\mathrm{Ti}}_{2}{mathrm{AlC}}\)和({{mathrm{(}{\mathrm{Ti}}_{1-x}{mathrm{Nb}}_{x})}_{2}{mathrm{AlC}}\)的 MAX 相为基础的靶材进行电弧沉积而获得的涂层的耐摩擦疲劳性。),其中 x = 0.1 和 0.2。在 20°C 时,所有涂层与 ShKh15 钢(1.0C-1.5Cr-0.3Ni-0.3Mn-0.3Si-0.25Cu)球接触时的摩擦系数和磨损比速率都大于所研究钢在 2 N 负荷下的摩擦系数和磨损比速率。与镍合金(17Cr-12W-11Fe-6Co-3Ti-1.5Nb-1.6Al)接触的带有({\mathrm{Ti}}_{2}{mathrm{AlC}}\)涂层的样品在高循环区域(N > \({10}^{5}\)循环)的抗摩擦疲劳性能明显高于无涂层样品。在 500°C 时,所有材料的摩擦学特性都有所下降,但使用了基于 \({\mathrm{Ti}}_{2}{mathrm{AlC}}\) 涂层的试样下降幅度最小。我们没有发现掺铌对这些涂层的耐磨性和抗摩擦疲劳性有积极影响。
Physicomechanical Properties of Coatings Based on Max Ti2AlC and (Ti, Nb)2AlC Phases at 20°C and 500°C
Physicomechanical characteristics of 15Kh16k5N2MVFAB-Sh steel (0.15C–16Cr–5Co–2Ni–0.7V–0.6Mo–0.3Nb–0.4N): wear resistance at 20°C and 500°C and resistance to fretting fatigue at 20°C without and with coatings obtained by the method of vacuum-arc deposition using targets based on the MAX phases of \({\mathrm{Ti}}_{2}{\mathrm{AlC}}\) and \({{\mathrm{(}{\mathrm{Ti}}}_{1-x}{\mathrm{Nb}}_{x})}_{2}{\mathrm{AlC}}\), where x = 0.1 and 0.2, are investigated. At 20°C the friction coefficient and the wear specific rate of all coatings are greater than that of the studied steel in contact with a ShKh15 steel (1.0C–1.5Cr–0.3Ni–0.3Mn–0.3Si–0.25Cu) ball under a load of 2 N. Unambiguous relationship between microhardness and tribological characteristics of materials has not been recorded. The resistance to fretting fatigue of the samples with \({\mathrm{Ti}}_{2}{\mathrm{AlC}}\) -based coating in contact with the Ni-alloy (17Cr–12W–11Fe–6Co–3Ti–1.5Nb–1.6Al) in high-cycle region (N > \({10}^{5}\) cycles) is significantly higher than that of uncoated samples. The tribological characteristics of all materials decrease at 500°C but the least for samples with \({\mathrm{Ti}}_{2}{\mathrm{AlC}}\) based coating. We have not found positive influence of niobium doping on the wear and fretting fatigue resistance of these coatings.
期刊介绍:
Materials Science reports on current research into such problems as cracking, fatigue and fracture, especially in active environments as well as corrosion and anticorrosion protection of structural metallic and polymer materials, and the development of new materials.