微重力低速气流引燃热厚固体燃料的数值研究

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-12-29 DOI:10.1007/s12217-023-10092-7
Kai Zhang, Feng Zhu, Shuangfeng Wang
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引用次数: 0

摘要

通过数值建模研究了固体材料在外部辐射加热条件下的引燃对低速流动的依赖机制。聚(甲基丙烯酸甲酯)(PMMA)被用作燃料。本研究的目的是深入了解固体燃料的内在点火机制,以及更全面地了解接近熄灭极限时点火过程的动力学特征。为此,我们使用火灾动态模拟器(FDS5)代码开发了一个二维数值模型,其中计算了固相和气相反应。研究了 16 kW/m2 和 25 kW/m2 两种辐射热流量,外部气流变化范围为 3 至 40 cm/s。模拟结果表明,当气体流速低于临界值时,瞬态气体反应在连续火焰附着在样品表面之前闪烁。随着流速的降低,闪焰时间(即在样品表面上方看到任何火焰的时间)会缩短,而闪焰持续时间会延长。在闪焰过程中,固体表面温度和质量流量迅速增加。点火时间(定义为燃料表面附着持续火焰的时间)会减少,达到最小值,然后增加,直到无法发生点火。为了解释点火时间与气流速度之间的 "V "型关系,研究人员考虑了各种机制,并确定了两种机制,每种机制都有不同的控制机制:一种是质量传输机制,点火延迟由氧气和热解酸盐的混合控制;另一种是热传递机制,点火延迟由对流热损失和点火临界质量通量的变化控制。随着气流速度的减小,临界质量通量呈现先减小后增大的趋势,这主要是由于热解酸盐和氧化剂的混合造成的,而临界温度则单调下降,这主要是由于燃料表面的净热通量减少造成的。研究结果进一步揭示了固体燃料在低速流动环境下的点火行为,为微重力环境下的消防安全提供了指导。
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Numerical Study on Pilot Ignition of a Thermally-Thick Solid Fuel with Low-Velocity Airflow in Microgravity

The mechanisms controlling the dependence on low-velocity flow of the piloted ignition of a solid material under external radiant heating is investigated through a numerical modeling. The poly (methyl methacrylate) (PMMA) was used as the fuel. The objective of the present study is to gain insight into the intrinsic ignition mechanisms of a solid fuel, as well as to gain a more comprehensive understanding of the dynamical characteristics of the ignition process near the extinction limit. For this purpose, a two-dimensional numerical model has been developed using the Fire Dynamic Simulator (FDS5) code, in which both solid-phase and gas-phase reactions are calculated. Two radiant heat flux, which are 16 and 25 kW/m2 were studied, and an external air flow was varied from 3 to 40 cm/s. The simulation results showed that transient gas reaction flashed before a continuous flame was attached to the sample surface for gas flow velocities lower than a critical value. As the flow velocity is reduced, the flashing time, which is defined as the time when any flame is seen above the sample surface, decreases, while the duration of flashing increases. The solid surface temperature and mass flow rate increase rapidly during flashing. The ignition time, which is defined as the time when a continuous flame is attached to the fuel surface, decreases, reaches a minimum, and then increases until ignition cannot occur. Mechanisms were considered to explain the ‘‘V-shaped” dependence of ignition time on flow-velocity, and two regimes were identified each having a different controlling mechanism: the mass transport regime where the ignition delay is controlled by the mixing of oxygen and pyrolyzate; and the heat transfer regime where the ignition delay is controlled by changes in convection heat losses and critical mass flux for ignition. With the decrease of the airflow velocity, the critical mass flux shows a trend of decreasing and then increasing, which is dominated by the mixing of the pyrolyzate and the oxidizer, while the critical temperature monotonically decreases, which is dominated by a reduction of the net heat flux at the fuel surface. The results provide further insight into the ignition behavior of solid fuel under low-velocity flow environment, and guidance about fire safety in microgravity environments.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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