{"title":"微重力低速气流引燃热厚固体燃料的数值研究","authors":"Kai Zhang, Feng Zhu, Shuangfeng Wang","doi":"10.1007/s12217-023-10092-7","DOIUrl":null,"url":null,"abstract":"<div><p>The mechanisms controlling the dependence on low-velocity flow of the piloted ignition of a solid material under external radiant heating is investigated through a numerical modeling. The poly (methyl methacrylate) (PMMA) was used as the fuel. The objective of the present study is to gain insight into the intrinsic ignition mechanisms of a solid fuel, as well as to gain a more comprehensive understanding of the dynamical characteristics of the ignition process near the extinction limit. For this purpose, a two-dimensional numerical model has been developed using the Fire Dynamic Simulator (FDS5) code, in which both solid-phase and gas-phase reactions are calculated. Two radiant heat flux, which are 16 and 25 kW/m<sup>2</sup> were studied, and an external air flow was varied from 3 to 40 cm/s. The simulation results showed that transient gas reaction flashed before a continuous flame was attached to the sample surface for gas flow velocities lower than a critical value. As the flow velocity is reduced, the flashing time, which is defined as the time when any flame is seen above the sample surface, decreases, while the duration of flashing increases. The solid surface temperature and mass flow rate increase rapidly during flashing. The ignition time, which is defined as the time when a continuous flame is attached to the fuel surface, decreases, reaches a minimum, and then increases until ignition cannot occur. Mechanisms were considered to explain the ‘‘V-shaped” dependence of ignition time on flow-velocity, and two regimes were identified each having a different controlling mechanism: the mass transport regime where the ignition delay is controlled by the mixing of oxygen and pyrolyzate; and the heat transfer regime where the ignition delay is controlled by changes in convection heat losses and critical mass flux for ignition. With the decrease of the airflow velocity, the critical mass flux shows a trend of decreasing and then increasing, which is dominated by the mixing of the pyrolyzate and the oxidizer, while the critical temperature monotonically decreases, which is dominated by a reduction of the net heat flux at the fuel surface. The results provide further insight into the ignition behavior of solid fuel under low-velocity flow environment, and guidance about fire safety in microgravity environments.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Numerical Study on Pilot Ignition of a Thermally-Thick Solid Fuel with Low-Velocity Airflow in Microgravity\",\"authors\":\"Kai Zhang, Feng Zhu, Shuangfeng Wang\",\"doi\":\"10.1007/s12217-023-10092-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The mechanisms controlling the dependence on low-velocity flow of the piloted ignition of a solid material under external radiant heating is investigated through a numerical modeling. The poly (methyl methacrylate) (PMMA) was used as the fuel. The objective of the present study is to gain insight into the intrinsic ignition mechanisms of a solid fuel, as well as to gain a more comprehensive understanding of the dynamical characteristics of the ignition process near the extinction limit. For this purpose, a two-dimensional numerical model has been developed using the Fire Dynamic Simulator (FDS5) code, in which both solid-phase and gas-phase reactions are calculated. Two radiant heat flux, which are 16 and 25 kW/m<sup>2</sup> were studied, and an external air flow was varied from 3 to 40 cm/s. The simulation results showed that transient gas reaction flashed before a continuous flame was attached to the sample surface for gas flow velocities lower than a critical value. As the flow velocity is reduced, the flashing time, which is defined as the time when any flame is seen above the sample surface, decreases, while the duration of flashing increases. The solid surface temperature and mass flow rate increase rapidly during flashing. The ignition time, which is defined as the time when a continuous flame is attached to the fuel surface, decreases, reaches a minimum, and then increases until ignition cannot occur. Mechanisms were considered to explain the ‘‘V-shaped” dependence of ignition time on flow-velocity, and two regimes were identified each having a different controlling mechanism: the mass transport regime where the ignition delay is controlled by the mixing of oxygen and pyrolyzate; and the heat transfer regime where the ignition delay is controlled by changes in convection heat losses and critical mass flux for ignition. With the decrease of the airflow velocity, the critical mass flux shows a trend of decreasing and then increasing, which is dominated by the mixing of the pyrolyzate and the oxidizer, while the critical temperature monotonically decreases, which is dominated by a reduction of the net heat flux at the fuel surface. The results provide further insight into the ignition behavior of solid fuel under low-velocity flow environment, and guidance about fire safety in microgravity environments.</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-12-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12217-023-10092-7\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s12217-023-10092-7","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Numerical Study on Pilot Ignition of a Thermally-Thick Solid Fuel with Low-Velocity Airflow in Microgravity
The mechanisms controlling the dependence on low-velocity flow of the piloted ignition of a solid material under external radiant heating is investigated through a numerical modeling. The poly (methyl methacrylate) (PMMA) was used as the fuel. The objective of the present study is to gain insight into the intrinsic ignition mechanisms of a solid fuel, as well as to gain a more comprehensive understanding of the dynamical characteristics of the ignition process near the extinction limit. For this purpose, a two-dimensional numerical model has been developed using the Fire Dynamic Simulator (FDS5) code, in which both solid-phase and gas-phase reactions are calculated. Two radiant heat flux, which are 16 and 25 kW/m2 were studied, and an external air flow was varied from 3 to 40 cm/s. The simulation results showed that transient gas reaction flashed before a continuous flame was attached to the sample surface for gas flow velocities lower than a critical value. As the flow velocity is reduced, the flashing time, which is defined as the time when any flame is seen above the sample surface, decreases, while the duration of flashing increases. The solid surface temperature and mass flow rate increase rapidly during flashing. The ignition time, which is defined as the time when a continuous flame is attached to the fuel surface, decreases, reaches a minimum, and then increases until ignition cannot occur. Mechanisms were considered to explain the ‘‘V-shaped” dependence of ignition time on flow-velocity, and two regimes were identified each having a different controlling mechanism: the mass transport regime where the ignition delay is controlled by the mixing of oxygen and pyrolyzate; and the heat transfer regime where the ignition delay is controlled by changes in convection heat losses and critical mass flux for ignition. With the decrease of the airflow velocity, the critical mass flux shows a trend of decreasing and then increasing, which is dominated by the mixing of the pyrolyzate and the oxidizer, while the critical temperature monotonically decreases, which is dominated by a reduction of the net heat flux at the fuel surface. The results provide further insight into the ignition behavior of solid fuel under low-velocity flow environment, and guidance about fire safety in microgravity environments.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.