{"title":"掺杂 Eu3+ 和碱金属离子的 Na5Y(WO4)4 的红色发光特性","authors":"Chenyuan Yuan, Guoying Feng, Qiangshen Chen","doi":"10.1515/zna-2023-0270","DOIUrl":null,"url":null,"abstract":"Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: 6 % Eu<jats:sup>3+</jats:sup>, 6 % R<jats:sup>+</jats:sup> (R = Li, Na, K) phosphors were synthesized using a high-temperature solid-state reaction method. Through a series of characterization methods, the crystal structure, morphology, composition, and luminescence properties of the sample are obtained. At the same time, the properties of Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: Eu<jats:sup>3+</jats:sup> phosphor added with alkali metal ions such as Li<jats:sup>+</jats:sup>, Na<jats:sup>+</jats:sup>, K<jats:sup>+</jats:sup> were also studied. The experiment showed the red light emission and fluorescence lifetime of Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: 6 % Eu<jats:sup>3+</jats:sup> are improved through the doping of low concentration alkali metal agents, and Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: 6 % Eu<jats:sup>3+</jats:sup>, 6 % Li<jats:sup>+</jats:sup> obtained the strongest red light emission intensity. The results indicate that the red emissions intensity of Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: Eu<jats:sup>3+</jats:sup> can be enhanced through the Li<jats:sup>+</jats:sup> alkali metal agents, which may lead to less use of Y<jats:sup>3+</jats:sup> and hence lower cost.","PeriodicalId":23871,"journal":{"name":"Zeitschrift für Naturforschung A","volume":"15 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Red luminescence properties of Na5Y(WO4)4 doped with Eu3+ and alkali metal ions\",\"authors\":\"Chenyuan Yuan, Guoying Feng, Qiangshen Chen\",\"doi\":\"10.1515/zna-2023-0270\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: 6 % Eu<jats:sup>3+</jats:sup>, 6 % R<jats:sup>+</jats:sup> (R = Li, Na, K) phosphors were synthesized using a high-temperature solid-state reaction method. Through a series of characterization methods, the crystal structure, morphology, composition, and luminescence properties of the sample are obtained. At the same time, the properties of Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: Eu<jats:sup>3+</jats:sup> phosphor added with alkali metal ions such as Li<jats:sup>+</jats:sup>, Na<jats:sup>+</jats:sup>, K<jats:sup>+</jats:sup> were also studied. The experiment showed the red light emission and fluorescence lifetime of Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: 6 % Eu<jats:sup>3+</jats:sup> are improved through the doping of low concentration alkali metal agents, and Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: 6 % Eu<jats:sup>3+</jats:sup>, 6 % Li<jats:sup>+</jats:sup> obtained the strongest red light emission intensity. The results indicate that the red emissions intensity of Na<jats:sub>5</jats:sub>Y(WO<jats:sub>4</jats:sub>)<jats:sub>4</jats:sub>: Eu<jats:sup>3+</jats:sup> can be enhanced through the Li<jats:sup>+</jats:sup> alkali metal agents, which may lead to less use of Y<jats:sup>3+</jats:sup> and hence lower cost.\",\"PeriodicalId\":23871,\"journal\":{\"name\":\"Zeitschrift für Naturforschung A\",\"volume\":\"15 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für Naturforschung A\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/zna-2023-0270\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für Naturforschung A","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/zna-2023-0270","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Red luminescence properties of Na5Y(WO4)4 doped with Eu3+ and alkali metal ions
Na5Y(WO4)4: 6 % Eu3+, 6 % R+ (R = Li, Na, K) phosphors were synthesized using a high-temperature solid-state reaction method. Through a series of characterization methods, the crystal structure, morphology, composition, and luminescence properties of the sample are obtained. At the same time, the properties of Na5Y(WO4)4: Eu3+ phosphor added with alkali metal ions such as Li+, Na+, K+ were also studied. The experiment showed the red light emission and fluorescence lifetime of Na5Y(WO4)4: 6 % Eu3+ are improved through the doping of low concentration alkali metal agents, and Na5Y(WO4)4: 6 % Eu3+, 6 % Li+ obtained the strongest red light emission intensity. The results indicate that the red emissions intensity of Na5Y(WO4)4: Eu3+ can be enhanced through the Li+ alkali metal agents, which may lead to less use of Y3+ and hence lower cost.