掺杂 Eu3+ 和碱金属离子的 Na5Y(WO4)4 的红色发光特性

Chenyuan Yuan, Guoying Feng, Qiangshen Chen
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摘要

采用高温固态反应方法合成了 Na5Y(WO4)4:6 % Eu3+、6 % R+(R = Li、Na、K)荧光粉。通过一系列表征方法,获得了样品的晶体结构、形貌、成分和发光特性。同时,还研究了加入 Li+、Na+、K+ 等碱金属离子的 Na5Y(WO4)4:Eu3+ 荧光粉的性质。实验结果表明,通过掺杂低浓度碱金属制剂,Na5Y(WO4)4: 6 % Eu3+荧光粉的红光发射和荧光寿命都得到了改善,其中 Na5Y(WO4)4: 6 % Eu3+、6 % Li+荧光粉的红光发射强度最强。结果表明,Na5Y(WO4)4:Eu3+ 的红光发射强度可通过 Li+ 碱金属剂得到提高,这可能会减少 Y3+ 的使用,从而降低成本。
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Red luminescence properties of Na5Y(WO4)4 doped with Eu3+ and alkali metal ions
Na5Y(WO4)4: 6 % Eu3+, 6 % R+ (R = Li, Na, K) phosphors were synthesized using a high-temperature solid-state reaction method. Through a series of characterization methods, the crystal structure, morphology, composition, and luminescence properties of the sample are obtained. At the same time, the properties of Na5Y(WO4)4: Eu3+ phosphor added with alkali metal ions such as Li+, Na+, K+ were also studied. The experiment showed the red light emission and fluorescence lifetime of Na5Y(WO4)4: 6 % Eu3+ are improved through the doping of low concentration alkali metal agents, and Na5Y(WO4)4: 6 % Eu3+, 6 % Li+ obtained the strongest red light emission intensity. The results indicate that the red emissions intensity of Na5Y(WO4)4: Eu3+ can be enhanced through the Li+ alkali metal agents, which may lead to less use of Y3+ and hence lower cost.
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