多壁碳纳米管与作为 DSSC 应用反电极的 NiO 和 pt

H. Ali
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摘要

利用水热法合成了 NiO-MWCNT,并将其用作染料敏化太阳能电池 DSSC 的低成本无铂对电极。基于 NiO-MWCNT 作为对电极的 DSSC 在 100 mW cm-2 (AM 1.5)的模拟太阳光照下实现了 8.53% 的高功率转换效率。这一效率与配备铂对电极的 DSSC 的 7.9% 不相上下。NiO-MWCNT 电极良好的电荷传导特性降低了电荷损耗,提高了将光能转化为电流的效率。此外,NiO-MWCNT 电极还能增强太阳能电池内部的光散射,从而增加光吸收并提高光能转化为电能的效率。NiO-MWCNT 电极的其他优点还包括成本低和可持续性强。与铂这种稀有而昂贵的材料相比,NiO-MWCNT 的使用降低了太阳能电池的成本,并有助于环境的可持续发展。此外,NiO-MWCNT 电极具有很高的化学稳定性,使其在染料太阳能电池环境中更耐腐蚀、更耐损坏。这就延长了电池的使用寿命,确保了电池的长期可持续性。
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Multi-Wall Carbon Nanotubes with NiO and pt as Counter Electrodes for DSSC applications
NiO-MWCNT was synthesized using the hydrothermal method and used as a low-cost, platinum-free counter electrode for Dye-sensitized solar cells DSSCs. The DSSC based on NiO-MWCNT as a counter electrode achieves a high-power conversion efficiency of 8.53% under a simulated solar illumination of 100 mW cm-2 (AM 1.5). This efficiency is comparable to 7.9% for a DSSC equipped with a Pt counter electrode. Good charge conduction characteristics of the NiO-MWCNT electrode decreases charge loss and boosts the effectiveness of converting light into electrical current. The NiO-MWCNT electrode also increases light absorption and increases the efficiency of converting light energy into electrical energy by enhancing light dispersion within the solar cell. Other advantages of NiO-MWCNT electrodes are low cost and great sustainability. Comparing it to platinum, rare and expensive material, the use of NiO-MWCNT reduces the cost of the solar cell and contributes to environmental sustainability. In addition, the NiO-MWCNT electrode has a high chemical stability, making it more resistant to corrosion and damage in dye solar cell environments. This enhances the lifespan of the cell and ensures its long-term sustainability.
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