Impact of the thickness of phthalocyanine films and its metal complexes on optical and electrical properties

The paper presents the results of a study of the structural, optical and electrophysical characteristics of phthalocyanine films and its metal complexes with different thicknesses. Films of phthalocyanine and its metal complexes were obtained on the conductive surface of the FTO by thermal evaporation in vacuum. It is shown that the observed broadening of the B and Q bands and the hypsochromic shift of the maxima in the absorption spectra are associated with the central atom. With a decrease in the thickness of MPc films, there is a decrease in the value of the half-width of the absorption spectra. The effect of the thickness of phthalocyanine films on the efficiency of generation and transport of charge carriers in the FTO/MPc/Al cell was studied. It is shown that the VAC increases almost 2.5 times compared to a photocell based on a metal-free phthalocyanine. From the obtained impedance measurement data, it was found that the electrophysical parameters of phthalocyanines depend on the values of optical density, broadening of absorption bands in the short-wave and visible spectral regions, which is consistent with the data of the volt-ampere characteristic.