Cr3+ 取代对 Co-Cu 和 Cu-Co 纳米铁氧体结构和形态特性的影响

D. Parajuli, N. Murali, K. Samatha
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引用次数: 0

摘要

采用溶胶-凝胶法制备了 Cr3+ 取代的 Co-Cu(Co0.7Cu0.3Fe2-xCrxO4)和 Cu-Co(Cu0.7Co0.3Fe2-xCrxO4)纳米铁氧体复合材料,其中 x = 0.0、0.05、0.1、0.15、0.2 和 0.25。分析了它们的结构、直流电阻率和磁性能。XRD 显示了单相尖晶石铁氧体。加入 Cr3+ 离子后,晶格体积和晶粒大小分别减小。FESEM 图像显示,非球形颗粒表面形状基本均匀,掺入 Cr3+ 后晶粒尺寸减小。傅立叶变换红外光谱图支持尖晶石铁氧体的 XRD 图。
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Cr3+ substitution effect on Co-Cu and Cu-Co nano ferrites on structural and morphological properties
The Cr3+ substituted Co-Cu (Co0.7Cu0.3Fe2-xCrxO4) and Cu-Co (Cu0.7Co0.3Fe2-xCrxO4) where x = 0.0, 0.05, 0.1, 0.15, 0.2 and 0.25 nano ferrite composite were prepared with the sol-gel approach. Their structural, dc electrical resistivity, and magnetic properties were analyzed. XRD shows the single-phase spinel ferrite. Adding Cr3+ ions decreases the lattice volume and the size of the crystallite respectively. FESEM images show non-spherical particles on a largely uniform surface shape with decreasing grain size on doping Cr3+. The FTIR pattern supports the XRD patterns for spinel ferrite.
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