通过机械研磨获得的超细粉末对铝氧化物和锆氧化物陶瓷材料密度的影响

P. M. Pletnev, E. S. Semantsova
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摘要

本文介绍了在各种研磨装置(球磨机、行星磨机和珠磨机)中研磨粉末状固体氧化锆和氧化铝的结果。研磨材料为:PSZ-5,5Y 牌(美国)部分钇稳定二氧化锆和 Almatis CT 3000 GS 牌(德国)α相含量超过 99.0 重量%的氧化铝。结果表明,为了获得高纯度、超细氧化物粉末,最好使用装有二氧化锆研磨球的珠磨机,研磨球的尺寸为 0.6-0.8 毫米,M : W 的比例为 1 : 4,研磨能量为 0.6-0.8 千瓦。实现初始氧化物粉末的超细状态可激活其固相烧结,提高陶瓷材料的密度:氧化铝的密度为 3.50-3.78 克/立方厘米,氧化锆的密度为 5.40-5.89 克/立方厘米。
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Effect of ultrafine powders obtained by mechanical grinding on the density of ceramic material made of aluminum and zirconium oxides
The results of grinding powdered, solid zirconium and aluminum oxides in various grinding units: ball, planetary and bead mills are presented. The grinding materials were: partially yttrium-stabilized zirconium dioxide of the PSZ-5,5Y brand (USA) and alumina with an alpha phase content of more than 99,0 wt. % of the brand Almatis CT 3000 GS (Germany). It is shown that in order to obtain high-purity, ultrafine oxide powders, it is advisable to use bead mills with zirconium dioxide grinding balls with dimensions of 0,6‒0,8 mm, with a ratio of M : W, as 1 : 4 and a specific grinding energy of 0,6‒0,8 kW. Achieving the ultrafine state of the initial oxide powders activates their solid-phase sintering, increases the density of ceramic materials: for aluminum oxide from 3,50‒3,78 g/cm3, for zirconium oxide from 5,40‒5,89 g/cm3.
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