无需任何额外假设的两种创新的内斯特方程推导方法

IF 1.8 4区 物理与天体物理 Q3 PHYSICS, APPLIED Modern Physics Letters B Pub Date : 2023-11-28 DOI:10.1142/s021798492450115x
S. Su, Shihao Xia, T. Liang, Jincan Chen
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引用次数: 0

摘要

研究发现,不需要任何额外的假设,就可以根据从超低温热力学系统中获得的实验数据重新推导出奈氏方程,这与教科书和文献中的推导过程不同,因此,奈氏方程所包含的物理内容不应称为奈氏公设或奈氏定理。它应更名为 "Nernst 声明"。这一发现对完善热力学理论框架将起到重要作用。它可以有效地防止一些人为假设进入热力学第三定律,使之成为客观世界的真实反映。它解决了一百多年来以热力学定理作为热力学定律核心内容所带来的尴尬问题。
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Two innovative derivation methods of the Nernst equation without any additional assumptions
It is found that without any additional assumptions, Nernst’s equation can be re-deduced from the experimental data obtained from the thermodynamic systems at ultra-low temperatures, which is different from the derivation processes in textbooks and literature, and consequently, the physical content included by Nernst’s equation should not be referred to as Nernst’s postulate or Nernst’s theorem. It should be renamed as the Nernst statement. This discovery will play an important role in improving the theoretical framework of thermodynamics. It can effectively prevent some artificial assumptions into the third law of thermodynamics, making it a true reflection of the objective world. It solves the awkward problem caused by using a thermodynamic theorem as the core contents of a thermodynamic law for over one hundred years.
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来源期刊
Modern Physics Letters B
Modern Physics Letters B 物理-物理:凝聚态物理
CiteScore
3.70
自引率
10.50%
发文量
235
审稿时长
5.9 months
期刊介绍: MPLB opens a channel for the fast circulation of important and useful research findings in Condensed Matter Physics, Statistical Physics, as well as Atomic, Molecular and Optical Physics. A strong emphasis is placed on topics of current interest, such as cold atoms and molecules, new topological materials and phases, and novel low-dimensional materials. The journal also contains a Brief Reviews section with the purpose of publishing short reports on the latest experimental findings and urgent new theoretical developments.
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