通过使用多种相容剂优化基于聚丙烯的复合材料中珍珠聚合物的表面相互作用

Çağrıalp Arslan, Ümit Tayfun, Mehmet Dogan
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摘要

聚合物与矿物添加剂之间的表面接触是影响矿物填充聚合物复合材料效率的最重要因素之一。在这项研究中,我们在聚丙烯(PP)和珍珠岩的复合材料中引入了三种不同的相容剂,以改善成分之间的相互作用。在含有 10% 膨胀珍珠岩的复合材料中,使用了三种不同比例的乙烯-醋酸乙烯共聚物(EVA)、热塑性聚氨酯弹性体(TPU)和马来酸酐接枝聚丙烯(MA-PP)相容剂。复合材料的生产采用先熔融混合后注塑成型的方法。根据机械、物理、动态机械评估和形态特征的结果,含有 MA-PP 相容剂的复合材料具有最出色的性能。研究结果表明,相容剂含量为 10%、添加量最低的复合材料的性能有所提高,而相容剂含量高的复合材料的性能则有所下降。根据这些结果可以确定,聚丙烯/珍珠岩复合材料体系中的相容剂通过提高熔体混合过程中确定的力值和熔体流速,有助于复合材料的制造。根据测试结果,就相容剂的效率而言,MA-PP 的表现优于 TPU 和 EVA。总体而言,在制造阶段选择 MA-PP 相容剂将在加工简易性和机械强度方面带来好处,其中膨胀珍珠岩将被用作聚丙烯基复合材料的天然填料。
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Optimizing perlite-polymer ınterface interactions in composites based on polypropylene via the utilization of several compatibilizers
The surface contact between the polymer and the mineral additive is one of the most significant aspects influencing the efficiency of mineral-filled polymeric composites. In this work, three distinct compatibilizers were introduced to composites based on polypropylene (PP) and perlite to improve interactions between the constituents. On composites comprising 10% expanded perlite content, three different ratios of ethylene vinyl acetate copolymer (EVA), thermoplastic polyurethane elastomer (TPU), and maleic anhydride grafted polypropylene (MA-PP) compatibilizers were employed. The composite was produced using an approach designated melt blending followed by injection molding. The composites containing MA-PP compatibilizer possessed the most outstanding performance, according to the results of mechanical, physical, and dynamic mechanical evaluations and morphological characterizations. The investigated aspects indicated a rise in the composites containing 10 percent compatibilizer with the lowest adding amount, whereas performances declined at high compatibilizer contents. Along with these results, it was determined that the compatibilizers included in the PP/perlite composite system assisted in the fabrication of the composites by promoting the force values and melt flow rates identified during melt mixing. Following the test outcomes, MA-PP performed better than TPU and EVA in terms of compatibilizer efficiency. In general, it has been revealed that the selection of MA-PP compatibilizer in the manufacturing stages would offer benefits in terms of both simplicity of processing and mechanical strength where expanded perlite will be adopted as a natural filler for PP-based composites.
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